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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Hair shampoos belong to which class of synthetic detergent?

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Dishwashing soaps are synthetic detergents. What is their chemical nature?

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Draw the diagram showing micelle formation by the following detergent.

\[\ce{CH3(CH2)10CH2OS\overset{-}{O}3\overset{+}{N}a}\]

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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How does the branching of hydrocarbon chain of synthetic detergents affect their biodegradability?

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Match structures given in Column I with the type of detergents given in Column II.

Column I Column II
(i) \[\ce{CH3(CH2)16COO(CH2CH2O) nCH2CH2OH}\] (a) Cationic detergent
(ii) \[\ce{C17H35COO- Na+}\] (b) Anionic detergent
(iii) \[\ce{CH3-(CH2)10CH2SO3- Na+}\] (c) Nonionic detergent

(iv) 

(d) Soap
[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Synthetic detergents have advantage over usual soaps as far as cleansing power is concerned. But use of synthetic detergents over a long time creates environmental pollution. How can the pollution caused by synthetic detergents be minimised? Classify the detergents according to their chemical nature.

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Convert the following: 

Propanenitrile to ethanol.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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In a coordination entity, the electronic configuration of the central metal ion is t2g3 eg1

Is the coordination compound a high spin or low spin complex?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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What is the no. of possible isomers for the octahedral complex [Co(NH3)2(C2O4)2]?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Which of the following tests/reactions is given by aldehydes as well as ketones?

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Using Valence bond theory, explain the following in relation to the paramagnetic complex [Mn(CN)6]3− 

  1. type of hybridization
  2. magnetic moment value
  3. type of complex – inner, outer orbital complex
[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Give reasons for the following observation:

Primary amine on treatment with benzenesulphonyl chloride forms a product which is soluble in NaOH however secondary amine gives product which is insoluble in NaOH.

[9] Amines
Chapter: [9] Amines
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What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).

[2] Electrochemistry
Chapter: [2] Electrochemistry
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A hydrocarbon (A) with molecular formula C5H10 on ozonolysis gives two products (B) and (C). Both (B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (B) give a silver mirror on reaction with Tollen’s reagent.

  1. Identify (A), (B) and (C).
  2. Write the reaction of B with Tollen’s reagent.
  3. Write the equation for iodoform test for C.
  4. Write down the equation for aldol condensation reaction of B and C.
[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Write chemical test to distinguish between the following compounds:

Phenol and Benzoic acid

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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A primary amine 'A' C2H7N reacts with alkyl halide (C2H5l) to give secondary amine 'B'. 'B' reacts with C6H5SO2Cl to give a solid 'C' which is insoluble in alkali. Identify 'A', 'B', 'C' and write all the chemical reaction involved.

[9] Amines
Chapter: [9] Amines
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Using valence bond theory, predict the hybridization and magnetic character of the following:

[CoF6]3– [Atomic number of Co = 27]

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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What is the composition of Fehling's reagent?

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Write the hybridisation and magnetic behaviour of [CoF6]3−.

[Given: Atomic number of Co = 27]

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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The reagent that can be used to distinguish acetophenone and benzophenone is ______.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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