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Hair shampoos belong to which class of synthetic detergent?
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Dishwashing soaps are synthetic detergents. What is their chemical nature?
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Draw the diagram showing micelle formation by the following detergent.
\[\ce{CH3(CH2)10CH2OS\overset{-}{O}3\overset{+}{N}a}\]
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How does the branching of hydrocarbon chain of synthetic detergents affect their biodegradability?
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Match structures given in Column I with the type of detergents given in Column II.
| Column I | Column II |
| (i) \[\ce{CH3(CH2)16COO(CH2CH2O) nCH2CH2OH}\] | (a) Cationic detergent |
| (ii) \[\ce{C17H35COO- Na+}\] | (b) Anionic detergent |
| (iii) \[\ce{CH3-(CH2)10CH2SO3- Na+}\] | (c) Nonionic detergent |
|
(iv) |
(d) Soap |
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Synthetic detergents have advantage over usual soaps as far as cleansing power is concerned. But use of synthetic detergents over a long time creates environmental pollution. How can the pollution caused by synthetic detergents be minimised? Classify the detergents according to their chemical nature.
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Convert the following:
Propanenitrile to ethanol.
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In a coordination entity, the electronic configuration of the central metal ion is t2g3 eg1
Is the coordination compound a high spin or low spin complex?
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What is the no. of possible isomers for the octahedral complex [Co(NH3)2(C2O4)2]?
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Which of the following tests/reactions is given by aldehydes as well as ketones?
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Using Valence bond theory, explain the following in relation to the paramagnetic complex [Mn(CN)6]3−
- type of hybridization
- magnetic moment value
- type of complex – inner, outer orbital complex
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Give reasons for the following observation:
Primary amine on treatment with benzenesulphonyl chloride forms a product which is soluble in NaOH however secondary amine gives product which is insoluble in NaOH.
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What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
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A hydrocarbon (A) with molecular formula C5H10 on ozonolysis gives two products (B) and (C). Both (B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (B) give a silver mirror on reaction with Tollen’s reagent.
- Identify (A), (B) and (C).
- Write the reaction of B with Tollen’s reagent.
- Write the equation for iodoform test for C.
- Write down the equation for aldol condensation reaction of B and C.
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Write chemical test to distinguish between the following compounds:
Phenol and Benzoic acid
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A primary amine 'A' C2H7N reacts with alkyl halide (C2H5l) to give secondary amine 'B'. 'B' reacts with C6H5SO2Cl to give a solid 'C' which is insoluble in alkali. Identify 'A', 'B', 'C' and write all the chemical reaction involved.
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Using valence bond theory, predict the hybridization and magnetic character of the following:
[CoF6]3– [Atomic number of Co = 27]
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What is the composition of Fehling's reagent?
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Write the hybridisation and magnetic behaviour of [CoF6]3−.
[Given: Atomic number of Co = 27]
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The reagent that can be used to distinguish acetophenone and benzophenone is ______.
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