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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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What should be the considerations during the extraction of metals by electrochemical method?

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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Which of the following acids forms three series of salts?

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Phosphorus forms a number of oxoacids. Out of these oxoacids phosphinic acid has strong reducing property. Write its structure and also write a reaction showing its reducing behaviour.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Which of the following statements are correct about the reaction intermediate?

(i) Intermediate (c) is unstable because in this carbon is attached to 5 atoms.

(ii) Intermediate (c) is unstable because carbon atom is sp2 hybridised.

(iii) Intermediate (c) is stable because carbon atom is sp2 hybridised.

(iv) Intermediate (c) is less stable than the reactant (b).

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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Draw other resonance structures related to the following structure and find out whether the functional group present in the molecule is ortho, para directing or meta directing.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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Why is it necessary to avoid even traces of moisture during the use of a Grignard reagent?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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The process of converting alkyl halides into alcohols involves ______.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Mark the correct increasing order of reactivity of the following compounds with HBr/HCl.

(a)
(b)
(c)
[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Name the factors responsible for the solubility of alcohols in water.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Suggest a reagent for the following conversion.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Alcohols react with active metals e.g. Na, K etc. to give corresponding alkoxides. Write down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Explain why is OH group in phenols more strongly held as compared to OH group in alcohols.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Explain why nucleophilic substitution reactions are not very common in phenols.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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In Kolbe’s reaction, instead of phenol, phenoxide ion is treated with carbon dioxide. Why?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Ethers can be prepared by Williamson synthesis in which an alkyl halide is reacted with sodium alkoxide. Di-tert-butyl ether can’t be prepared by this method. Explain.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Why is the C – O – H bond angle in alcohols slightly less than the tetrahedral angle whereas the C – O – C bond angle in ether is slightly greater?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Assertion: Bond angle in ethers is slightly less than the tetrahedral angle.

Reason: There is a repulsion between the two bulky (–R) groups.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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The gas evolved when methylamine reacts with nitrous acid is:

[9] Amines
Chapter: [9] Amines
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Acid anhydrides on reaction with primary amines give ______.

[9] Amines
Chapter: [9] Amines
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Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

[10] Biomolecules
Chapter: [10] Biomolecules
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