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Write a chemical equation for combustion reaction of the following hydrocarbon:
Pentene
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Write a chemical equation for combustion reaction of the following hydrocarbon:
Hexyne
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Write a chemical equation for combustion reaction of the following hydrocarbon:
Toluene
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Explain the following reaction.
Silicon dioxide is treated with hydrogen fluoride.
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If the starting material for the manufacture of silicones is RSiCl3, write the structure of the product formed.
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Bromine monochloride, BrCl decomposes into bromine and chlorine and reaches the equilibrium:
\[\ce{2BrCl (g) ⇌ Br2 (g) + Cl2 (g)}\]
for which Kc= 32 at 500 K. If initially pure BrCl is present at a concentration of 3.3 × 10–3 molL–1, what is its molar concentration in the mixture at equilibrium?
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Which of the two: O2NCH2CH2O– or CH3CH2O–is expected to be more stable and why?
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What is meant by ‘demineralised’?
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Is demineralised or distilled water useful for drinking purposes? If not, how can it be made useful?
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Which of the following pair of elements would have a more negative electron gain enthalpy?
O or F
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how can demineralised be obtained?
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Wavelengths of different radiations are given below:
λ(A) 300 nm, λ(B) 300 µm, λ(C) 3 nm, λ(D) = 30 A°
Arrange these radiations in the increasing order of their energies.
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Match the following
| (i) X-rays | (a) ν = 100 – 104 Hz |
| (ii) UV | (b) v = 1010 Hz |
| (iii) Long radio waves | (c) v = 1016 Hz |
| (iv) Microwave | (d) v = 1018 Hz |
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Among halogens, the correct order of amount of energy released in electron gain (electron gain enthalpy) is ______.
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The formation of the oxide ion, \[\ce{O2- (g)}\], from oxygen atom requires first an exothermic and then an endothermic step as shown below:
\[\ce{O (g) + e- -> O- (g) ; ∆H^Θ = - 14 kJ mol^{-1}}\]
\[\ce{O- (g) + e- -> O^{2-} (g) ; ∆H^Θ = + 780 kJ mol^{-1}}\]
Thus process of formation of \[\ce{O^{2-}}\] in gas phase is unfavourable even though \[\ce{O^{2-}}\] is isoelectronic with neon. It is due to the fact that,
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Which of the following elements will gain one electron more readily in comparison to other elements of their group?
(i) \[\ce{S (g)}\]
(ii) \[\ce{Na (g)}\]
(iii) \[\ce{O (g)}\]
(iv) \[\ce{Cl (g)}\]
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Which of the following statements are correct?
(i) Helium has the highest first ionisation enthalpy in the periodic table.
(ii) Chlorine has less negative electron gain enthalpy than fluorine.
(iii) Mercury and bromine are liquids at room temperature.
(iv) In any period, atomic radius of alkali metal is the highest.
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In which of the following options the order of arrangement does not agree with the variation of the property indicated against it?
(i) \[\ce{Al^{3+} < Mg^{2+} < Na+ < F-}\] (increasing ionic size)
(ii) \[\ce{B < C < N < O}\] (increasing first ionisation enthalpy)
(iii) \[\ce{I < Br < Cl < F}\] (increasing electron gain enthalpy)
(iv) \[\ce{Li < Na < K < Rb}\] (increasing metallic radius)
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Explain why the electron gain enthalpy of fluorine is less negative than that of chlorine.
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Match the correct ionisation enthalpies and electron gain enthalpies of the following elements.
| Elements | ∆H1 | ∆H2 | ∆egH | |
| (i) Most reactive non-metal | A. | 419 | 3051 | – 48 |
| (ii) Most reactive metal | B. | 1681 | 3374 | – 328 |
| (iii) Least reactive element e | C. | 738 | 1451 | – 40 |
| (iv) Metal forming binary halide | D. | 2372 | 5251 | + 48 |
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