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Science (English Medium) Class 11 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Write a chemical equation for combustion reaction of the following hydrocarbon: 

Pentene 

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Write a chemical equation for combustion reaction of the following hydrocarbon:

Hexyne

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Write a chemical equation for combustion reaction of the following hydrocarbon:

Toluene

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Explain the following reaction.

Silicon dioxide is treated with hydrogen fluoride.

[11] Some P-block Elements
Chapter: [11] Some P-block Elements
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If the starting material for the manufacture of silicones is RSiCl3, write the structure of the product formed.

[11] Some P-block Elements
Chapter: [11] Some P-block Elements
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Bromine monochloride, BrCl decomposes into bromine and chlorine and reaches the equilibrium:

\[\ce{2BrCl (g) ⇌ Br2 (g) + Cl2 (g)}\]

for which Kc= 32 at 500 K. If initially pure BrCl is present at a concentration of 3.3 × 10–3 molL–1, what is its molar concentration in the mixture at equilibrium?

[6] Equilibrium
Chapter: [6] Equilibrium
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Which of the two: O2NCH2CH2O or CH3CH2Ois expected to be more stable and why?

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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What is meant by ‘demineralised’?

[9] Hydrogen
Chapter: [9] Hydrogen
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Is demineralised or distilled water useful for drinking purposes? If not, how can it be made useful?

[9] Hydrogen
Chapter: [9] Hydrogen
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Which of the following pair of elements would have a more negative electron gain enthalpy?

O or F

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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how can demineralised be obtained?

[9] Hydrogen
Chapter: [9] Hydrogen
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Wavelengths of different radiations are given below:

λ(A) 300 nm, λ(B) 300 µm, λ(C) 3 nm, λ(D) = 30 A°

Arrange these radiations in the increasing order of their energies.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Match the following

(i) X-rays (a) ν =  100 – 104 Hz
(ii) UV (b) v = 1010 Hz
(iii) Long radio waves (c) v = 1016 Hz
(iv) Microwave (d)  v = 1018 Hz
[2] Structure of Atom
Chapter: [2] Structure of Atom
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Among halogens, the correct order of amount of energy released in electron gain (electron gain enthalpy) is ______.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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The formation of the oxide ion, \[\ce{O2- (g)}\], from oxygen atom requires first an exothermic and then an endothermic step as shown below:

\[\ce{O (g) + e- -> O- (g) ; ∆H^Θ = - 14 kJ mol^{-1}}\]

\[\ce{O- (g) + e- -> O^{2-} (g) ; ∆H^Θ = + 780 kJ mol^{-1}}\]

Thus process of formation of \[\ce{O^{2-}}\] in gas phase is unfavourable even though \[\ce{O^{2-}}\] is isoelectronic with neon. It is due to the fact that,

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Which of the following elements will gain one electron more readily in comparison to other elements of their group?

(i) \[\ce{S (g)}\]

(ii) \[\ce{Na (g)}\]

(iii) \[\ce{O (g)}\]

(iv) \[\ce{Cl (g)}\]

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Which of the following statements are correct?

(i) Helium has the highest first ionisation enthalpy in the periodic table.

(ii) Chlorine has less negative electron gain enthalpy than fluorine.

(iii) Mercury and bromine are liquids at room temperature.

(iv) In any period, atomic radius of alkali metal is the highest.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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In which of the following options the order of arrangement does not agree with the variation of the property indicated against it?

(i) \[\ce{Al^{3+} < Mg^{2+} < Na+ < F-}\] (increasing ionic size)

(ii) \[\ce{B < C < N < O}\] (increasing first ionisation enthalpy)

(iii) \[\ce{I < Br < Cl < F}\] (increasing electron gain enthalpy)

(iv) \[\ce{Li < Na < K < Rb}\] (increasing metallic radius)

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Explain why the electron gain enthalpy of fluorine is less negative than that of chlorine.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Match the correct ionisation enthalpies and electron gain enthalpies of the following elements.

Elements   ∆H1 ∆H2 egH
(i) Most reactive non-metal A. 419 3051 – 48
(ii) Most reactive metal B. 1681 3374 – 328
(iii) Least reactive element e C. 738 1451 – 40
(iv) Metal forming binary halide D. 2372 5251 + 48
[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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