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Write the chemical equations involved in the following reactions:
Carbylamine reaction
Concept: Concept of Amines >> Chemical Reactions of Amines - Carbylamine Reaction
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Concept: Physical Properties of Amines
What is the difference between a nucleoside and nucleotide?
Concept: Biomolecules in the Cell > Nucleic Acids >> Structure of Nucleic Acids
What is the difference between fibrous protein and globular protein ?
Concept: Introduction of Proteins
Write the product obtained when D-glucose reacts with H2N − OH.
Concept: Biomolecules in the Cell > Carbohydrates >> Monosaccahrides
Due to hectic and busy schedule, Mr Angad made his life full of tensions and anxiety. He started taking sleeping pills to overcome the depression without consulting the doctor. Mr Deepak, a close friend of Mr. Angad advised him to stop taking sleeping pills and suggested to change his life lifestyle by doing yoga, meditation and some physical exercise. Mr. Angad followed his friend’s advice and after few days he started feeling better.
After reading the above passage, answer the following
(i) What are the values (at least two) displayed by Mr. Deepak?
(ii) Why is it not advisable to take sleeping pills without consulting doctor?
(iii) What are tranquilisers? Give two examples.
Concept: Classification of Drugs
What is ferromagnetism?
Concept: Properties of Solids: Magnetic Properties
What type of magnetism is shown by a substance if magnetic moments of domains are arranged in same direction?
Concept: Properties of Solids: Magnetic Properties
An element crystallizes in a f.c.c. lattice with a cell edge of 250 pm. Calculate the density if 300 g of this element contains 2 × 1024 atoms.
Concept: Calculations Involving Unit Cell Dimensions
Calculate the freezing point of solution when 1.9 g of MgCl2 (M = 95 g mol−1) was dissolved in 50 g of water, assuming MgCl2 undergoes complete ionization.
(Kf for water = 1.86 K kg mol−1)
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why?
Concept: Colligative Properties and Determination of Molar Mass >> Elevation of Boiling Point
What happens when the external pressure applied becomes more than the osmotic pressure of solution?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate the formula of sulphur (Sx).
(Kf for CS2 = 3.83 K kg mol−1, Atomic mass of sulphur = 32 g mol−1]
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd of tetrahedral voids?
Concept: Crystal Lattices and Unit Cells
What is meant by positive deviations from Raoult's law? Give an example. What is the sign of ∆mixH for positive deviation?
Concept: Vapour Pressure of Liquid >> Vapour Pressure of Liquid- Liquid Solutions
3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van't Hoff factor and predict the nature of solute (associated or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol−1, Kf for benzene = 4.9 K kg mol−1)
Concept: Abnormal Molar Masses
An element with molar mass 27 g mol−1 forms a cubic unit cell with edge length 4.05 ✕ 10−8 cm. If its density is 2.7 g cm−3, what is the nature of the cubic unit cell?
Concept: Number of Atoms in a Unit Cell
Define the following term
Schottky defect
Concept: Imperfections in Solids - Introduction
An element with density 2.8 g cm–3 forms a f.c.c. unit cell with edge length 4 x 10–8 cm. Calculate the molar mass of the element.
(Given : NA = 6.022 x 1023 mol –1)
Concept: Calculations Involving Unit Cell Dimensions
