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HSC Science (Computer Science) इयत्ता १२ वी - Maharashtra State Board Question Bank Solutions for Chemistry

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Chemistry
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What is the action of the following reagents on aniline?

Bromine water

[13.01] Amines
Chapter: [13.01] Amines
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Draw the geometrical isomers of complex [Pt(NH3)2Cl2].

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
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Write the cell representation and calculate equilibrium constant for the following redox reaction:

`Ni_((s))+2Ag_((aq))^+ (1M)->Ni_((aq))^(2+)(1M)+2Ag_((s)) " at "25^@ C`

`E_(ni)^+`=-0.25V and `E_(Ag)^+=0.799V`

[4] Electrochemistry
Chapter: [4] Electrochemistry
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What is the action of acetic anhydride on diethylamine?

[13.01] Amines
Chapter: [13.01] Amines
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What is the action of the following reagents on aniline?

Acetic anhydride

 

[13.01] Amines
Chapter: [13.01] Amines
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What is the action of the following reagents on aniline?

Hot and conc. sulphuric acid

[13.01] Amines
Chapter: [13.01] Amines
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Write applications of electrochemical series.

[5] Electrochemistry
Chapter: [5] Electrochemistry
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Answer the following:

Identify oxidising agents and arrange them in order of increasing strength under standard state conditions. The standard potentials are given in parenthesis.

Al  (–1.66V), Al3+(–1.66V),  Cl2  (1.36V),  Cd2+ (–0.4V), Fe (–0.44V),  I2 (0.54V),  Br- (1.09V).

[5] Electrochemistry
Chapter: [5] Electrochemistry
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Answer the following:

Which of the following species are reducing agents? Arrange them in order of increasing strength under standard state conditions. The standard potentials are given in parenthesis.

K (–2.93V),  Br2(1.09V), Mg(–2.36V), Ce3+(1.61V), Ti2+(–0.37V), Ag+ (0.8 V), Ni (–0.23V).

[5] Electrochemistry
Chapter: [5] Electrochemistry
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Answer the following in brief.

How a catalyst increases the rate of reaction? Explain with the help of a potential energy diagram for catalyzed and uncatalyzed reactions.

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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Answer the following:

Predict whether the following reaction would occur spontaneously under standard state condition.

\[\ce{2Ag_{(s)} + Ni^{2+}_{ (aq)} -> 2Ag^{+}_{ (aq)} + Ni_{(s)}}\]

[5] Electrochemistry
Chapter: [5] Electrochemistry
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Answer the following in brief.

Explain graphically the effect of a catalyst on the rate of reaction.

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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Answer the following

Iron exhibits +2 and +3 oxidation states. Write their electronic configuration. Which will be more stable? Why ?

[8] Transition and Inner Transition Elements
Chapter: [8] Transition and Inner Transition Elements
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Answer the following

Give the similarities and differences in elements of 3d, 4d, and 5d series.

[8] Transition and Inner Transition Elements
Chapter: [8] Transition and Inner Transition Elements
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Write two applications of electrochemical series.

[5] Electrochemistry
Chapter: [5] Electrochemistry
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Discuss the position of d-block elements, lanthanoids and actinoids in the periodic table.

[8] Transition and Inner Transition Elements
Chapter: [8] Transition and Inner Transition Elements
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Define electrochemical series. 

[5] Electrochemistry
Chapter: [5] Electrochemistry
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How is ethyl amine prepared from methyl iodide?

[13.01] Amines
Chapter: [13.01] Amines
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How are propan-1-amine and propan-2-amine prepared from oxime?

[13.01] Amines
Chapter: [13.01] Amines
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The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `

(A) linkage isomer

(B) ionisation isomer

(C) co-ordination isomer

(D) geometrical isomer

 
[9] Coordination Compounds
Chapter: [9] Coordination Compounds
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