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The statement that is not correct for periodic classification of elements is ______.
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All transition elements are d-block elements, but all d-block elements are not transition elements. Explain
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In which of the following molecule/ion all the bonds are not equal?
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Which of the following statements are correct about \[\ce{CO^{2-}3}\]?
(i) The hybridisation of central atom is sp3.
(ii) Its resonance structure has one \[\ce{C - O}\] single bond and two \[\ce{C = O}\] double bonds.
(iii) The average formal charge on each oxygen atom is 0.67 units.
(iv) All \[\ce{C - O}\] bond lengths are equal.
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All the \[\ce{C - O}\] bonds in carbonate ion \[\ce{(CO^{2-}3)}\] are equal in length. Explain.
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Describe hybridisation in the case of \[\ce{PCl5}\] and \[\ce{SF6}\]. The axial bonds are longer as compared to equatorial bonds in \[\ce{PCl5}\] whereas in \[\ce{SF6}\] both axial bonds and equatorial bonds have the same bond length. Explain.
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Which of the following arrangements represent increasing oxidation number of the central atom?
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Assertion (A): Among halogens fluorine is the best oxidant.
Reason (R): Fluorine is the most electronegative atom.
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Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as oxidising agent.
Reason (R): Oxidation state of manganese changes from +2 to +7 during the reaction.
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Which of the following equations depict the oxidising nature of \[\ce{H2O2}\]?
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Which of the following equation depicts reducing nature of \[\ce{H2O2}\]?
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Some of the properties of water are described below. Which of them is/are not correct?
(i) Water is known to be a universal solvent.
(ii) Hydrogen bonding is present to a large extent in liquid water.
(iii) There is no hydrogen bonding in the frozen state of water.
(iv) Frozen water is heavier than liquid water.
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If same mass of liquid water and a piece of ice is taken, then why is the density of ice less than that of liquid water?
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Give reasons: Lakes freeze from top towards bottom.
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Give reasons: Ice floats on water.
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\[\ce{H2O2}\] is a better oxidising agent than water. Explain.
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Melting point, enthalpy of vapourisation and viscosity data of \[\ce{H2O}\] and \[\ce{D2O}\] is given below :
| \[\ce{H, O}\] | \[\ce{D2O}\] | |
| Melting point / K | 373.0 | 374.4 |
| Enthalpy of vapourisation at (373 K)/kJ mol–1 | 40.66 | 41.61 |
| Viscosity/centipoise | 0.8903 | 1.107 |
On the basis of this data explain in which of these liquids intermolecular forces are stronger?
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Explain why \[\ce{HCl}\] is a gas and \[\ce{HF}\] is a liquid.
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Why does water show high boiling point as compared to hydrogen sulphide? Give reasons for your answer.
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How will you account for 104.5° bond angle in water?
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