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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write a mathematical expression for integrated rate law for zero order reaction.

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प्रश्न

Write a mathematical expression for integrated rate law for zero-order reaction.

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उत्तर

The mathematical expression for integrated rate law for zero-order reaction is kt = [A]0 - [A]t.

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पाठ 6: Chemical Kinetics - Very short answer questions

संबंधित प्रश्‍न

Answer the following in one or two sentences.

What are the units for rate constants for zero-order and second-order reactions if time is expressed in seconds and concentration of reactants in mol/L?


Answer the following in brief.

Obtain the relationship between the rate constant and half-life of a first-order reaction.


Answer the following in brief.

How will you represent the zeroth-order reaction graphically?


How will you represent first order reactions graphically.


Answer the following in brief.

What are the units of the rate constant?


Explain with the help of a potential energy diagram that the catalyst increases the rate of the reaction.


Derive an integrated rate law expression for first order reaction: A → B + C


Write units of rate constants for:

  1. First-order reaction
  2. Zero-order reaction

For a first-order reaction \[\ce{A -> B}\] the rate constant is x min−1. If the initial concentration of A is 0.01 M, the concentration of A after one hour is given by the expression.


A zero-order reaction \[\ce{X -> Product}\], with an initial concentration 0.02 M has a half-life of 10 min. if one starts with concentration 0.04 M, then the half-life is


Give two examples for zero order reaction.


A zero order reaction is 20% complete in 20 minutes. Calculate the value of the rate constant. In what time will the reaction be 80% complete?


What is the order of reaction if the unit of rate constant (k) is mol dm−3 s−1?


If time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 hours, the half life of this first order reaction is ____________.


Which of the following represents the expression for `(3/4)^"th"` life of 1st order reaction?


For first order reaction the slope of the graph of log10 [A]t Vs. time is equal to ____________.


In the reaction \[\ce{2SO2 + O2 -> 2SO3}\] the rate of appearance of SO3 is 4 × 10−4 M/s, the rate of disappearance of O2 is ____________.


Reaction given below follows first order kinetics:

\[\ce{2N2O2 -> 4NO2 + O2}\]

Calculate the rate constant of reaction if concentration of N2O2 is 0.05 M and rate of reaction is 1.5 × 10−6 mol L−1 s−1?


For a zero order reaction, the plot of [A]t vs t is linear. The slope of the line is equal to ____________.


The half-life of a first order reaction is 6.0 hour. How long will it take for the concentration of reactant to decrease from 0.4 M to 0.12 M?


A first order reaction takes 40 minutes for 30% completion. Calculate the half-life of reaction.


A first order reaction, A → B takes 100 minutes for it's 90% completion. What is the rate constant of reaction?


Half-life of first-order reaction \[\ce{X -> Y + Z}\] is 3 minutes. What is the time required to reduce the concentration of 'X' by 90 % of it's initial concentration?


Rate constant for zero order reaction is 2 × 10-2 mol L-1 s-1. If the concentration of the reactant after 25 sec. is 0.5 M, what is the initial concentration of reactant?


For zero order reaction, when [A]t is plotted against time (t), the slope of the straight line obtained is equal to ______.


Which one of the following reactions is a true first-order reaction?


The half-life of first order reaction is 1.7 hour. What is its rate constant?


For a first order reaction, the plot of log k against 1/T is a straight line. The slope of the line is equal to ______.


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