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प्रश्न
Which of the following concentration terms is/are independent of temperature
पर्याय
molality
molarity
mole fraction
molality and molarity
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उत्तर
molality and molarity
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संबंधित प्रश्न
Suggest the most important type of intermolecular attractive interaction in the following pair.
Acetonitrile (CH3CN) and acetone (C3H6O)
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal, `P_"chloroform"` and `P_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:
| `bb(100 xx chi_"acetone")` | `bb(P_"acetone"//"mm Hg")` | `bb(P_"chloroform"//"mm Hg")` |
| 0 | 0 | 632.8 |
| 11.8 | 54.9 | 548.1 |
| 23.4 | 110.1 | 469.4 |
| 36.0 | 202.4 | 359.7 |
| 50.8 | 322.7 | 257.7 |
| 58.2 | 405.9 | 193.6 |
| 64.5 | 454.1 | 161.2 |
| 72.1 | 521.1 | 120.7 |
Plot this data also on the same graph paper. Indicate whether it has a positive or negative deviation from the ideal solution.
The KH for the solution of oxygen dissolved in water is 4 × 104 atm at a given temperature. If the partial pressure of oxygen in air is 0.4 atm, the mole fraction of oxygen in solution is ______.
Two liquids X and Y on mixing gives a warm solution. The solution is ______.
Assertion: An ideal solution obeys Raoults Law.
Reason: In an ideal solution, solvent – solvent as well as solute – solute interactions are similar to solute-solvent interactions.
Intermolecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?
(i) ∆mix H = zero
(ii) ∆mix V = zero
(iii) These will form minimum boiling azeotrope.
(iv) These will not form ideal solution.
Concentration terms such as mass percentage, ppm, mole fraction and molality are independent of temperature, however molarity is a function of temperature. Explain.
Why soda water bottle kept at room temperature fizzes on opening?
Assertion: When a solution is separated from the pure solvent by a semipermeable membrane, the solvent molecules pass through it from pure solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration solution to a region of low concentration solution.
Upon increase in pressure for dissociation N2O4 into NO2, equilibrium shift towards
