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Which cell will measure standard electrode potential of copper electrode? - Chemistry

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प्रश्न

Which cell will measure standard electrode potential of copper electrode?

पर्याय

  • \[\ce{Pt(s) | H2 (g,0.1 bar) | H+ (aq; 1 M) || Cu^{2+} (aq;1M) | Cu}\]

  • \[\ce{Pt(s) | H2 (g, 1 bar) | H+ (aq; 1 M) || Cu^{2+} (aq; 2 M) | Cu}\]

  • \[\ce{Pt(s) | H2 (g, 1 bar) | H+ (aq; 1 M) || Cu^{2+} (aq; 1 M) | Cu}\]

  • \[\ce{Pt(s) | H2 (g, 1 bar) | H+ (aq; 0.1 M) || Cu^{2+} (aq; 1 M) | Cu}\]

MCQ
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उत्तर

\[\ce{Pt(s) | H2 (g, 1 bar) | H+ (aq; 1 M) || Cu^{2+} (aq; 1 M) | Cu}\]

Explanation:

When copper electrode is connected to standard hydrogen electrode, it acts as cathode and its standard electrode potential can be measured.

`"E"^0 = "E"_"R"^0 - "E"_"L"^0 = "E"_"R"^0 - 0 = "E"_"R"^0`

To calculate the standard electrode potential of the given cell it is coupled with the standard hydrogen electrode in which pressure of hydrogen gas is one bar and the cone, of H+ ion in the solution is one molar and also the concentrations of the oxidized and the reduced forms of the species in the right-hand half-cell are unity.

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पाठ 3: Electrochemistry - Exercises [पृष्ठ ३३]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 3 Electrochemistry
Exercises | Q I. 1. | पृष्ठ ३३

संबंधित प्रश्‍न

Draw a neat and well labelled diagram of primary reference electrode.


Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer 

Element

Al(s)

Cu(s)

Cl(aq)

Ni(s)

 

Eo

-1.66V

0.34V

1.36V

-0.26V

 


Calculate Ecell and ΔG for the following at 28°C :

Mg(s) + Sn2+( 0.04M ) → Mg2+( 0.06M ) + Sn(s)

cell = 2.23V. Is the reaction spontaneous ?


Calculate emf of the following cell at 25°C:

\[\ce{Sn/Sn^2+ (0.001 M) || H+ (0.01 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]

Given: \[\ce{E^\circ(Sn^2+/sn) = -0.14 V, E^\circ H+/H2 = 0.00 V (log 10 = 1)}\]


Given the standard electrode potentials,

K+/K = −2.93 V, Ag+/Ag = 0.80 V,

Hg2+/Hg = 0.79 V

Mg2+/Mg = −2.37 V, Cr3+/Cr = −0.74 V

Arrange these metals in their increasing order of reducing power.


Depict the galvanic cell in which the reaction \[\ce{Zn(s) + 2Ag+(aq) → Zn^{2+}(aq) + 2Ag(s)}\] takes place. Further show:

  1. Which of the electrode is negatively charged?
  2. The carriers of the current in the cell.
  3. Individual reaction at each electrode.

In the representation of the galvanic cell, the ions in the same phase are separated by a _______.


Galvanic or a voltaic cell converts the chemical energy liberated during a redox reaction to ____________.


Standard electrode potential is measured taking the concentrations of all the species involved in a half-cell is ____________.


Use the data given in below find out which of the following is the strongest oxidising agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


The positive value of the standard electrode potential of Cu2+/Cu indicates that:

(i) this redox couple is a stronger reducing agent than the H+/H2 couple.

(ii) this redox couple is a stronger oxidising agent than H+/H2 .

(iii) Cu can displace H2 from acid.

(iv) Cu cannot displace H2 from acid.


What does the negative sign in the expression `"E"^Θ ("Zn"^(2+))//("Zn")` = − 0.76 V mean?


Value of standard electrode potential for the oxidation of \[\ce{Cl-}\] ions is more positive than that of water, even then in the electrolysis of aqueous sodium chloride, why is \[\ce{Cl-}\] oxidised at anode instead of water?


Which reference electrode is used to measure the electrode potential of other electrodes?


Assertion: Cu is less reactive than hydrogen.

Reason: `E_((Cu^(2+))/(Cu))^Θ` is negative.


Represent the cell in which the following reaction takes place.The value of E˚ for the cell is 1.260 V. What is the value of Ecell?

\[\ce{2Al (s) + 3Cd^{2+} (0.1M) -> 3Cd (s) + 2Al^{3+} (0.01M)}\]


Which is the correct order of second ionization potential of C, N, O and F in the following?


Standard electrode potential of three metals X, Y and Z are –1.2 V, +0.5 V and –3.0 V, respectively. The reducing power of these metals will be ______.


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