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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Using the data given below find out the strongest reducing agent. E0cr2O12-Cr3+ = 1.33V E0Cl2Cl- = 1.36V E0MnO4-MN2+ = 1.51V E0Cr3+Cr = – 0.74V - Chemistry

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प्रश्न

Using the data given below find out the strongest reducing agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖` = 1.33 V  `"E"_("Cl"_2//"Cl"^-) = 1.36` V

`"E"_("MnO"_4^-//"Mn"^(2+))` = 1.51 V  `"E"_("Cr"^(3+)//"Cr")` = - 0.74 V

पर्याय

  • Cl 

  • Cr

  • Cr3+ 

  • Mn2+ 

MCQ
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उत्तर

Cr

Explanation:

A negative value of standard reduction potential for Cr3+ to Cr means that the redox couple is a stronger reducing agent.

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पाठ 3: Electrochemistry - Exercises [पृष्ठ ३४]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 3 Electrochemistry
Exercises | Q I. 8. | पृष्ठ ३४

संबंधित प्रश्‍न

Draw a neat and well labelled diagram of primary reference electrode.


Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer 

Element

Al(s)

Cu(s)

Cl(aq)

Ni(s)

 

Eo

-1.66V

0.34V

1.36V

-0.26V

 


Calculate Ecell and ΔG for the following at 28°C :

Mg(s) + Sn2+( 0.04M ) → Mg2+( 0.06M ) + Sn(s)

cell = 2.23V. Is the reaction spontaneous ?


The standard e.m.f of the following cell is 0.463 V

`Cu|Cu_(1m)^(++)`

What is the standard potential of Cu electrode?

(A) 1.137 V

(B) 0.337 V

(C) 0.463 V

(D) - 0.463 V


Calculate e.m.f of the following cell at 298 K:

2Cr(s) + 3Fe2+ (0.1M) → 2Cr3+ (0.01M) + 3 Fe(s)

Given: E°(Cr3+ | Cr) = – 0.74 VE° (Fe2+ | Fe) = – 0.44 V


Given the standard electrode potentials,

K+/K = −2.93 V, Ag+/Ag = 0.80 V,

Hg2+/Hg = 0.79 V

Mg2+/Mg = −2.37 V, Cr3+/Cr = −0.74 V

Arrange these metals in their increasing order of reducing power.


Calculate the emf of the following cell at 25°C :

\[{E^0}_\left( {Zn}^{2 +} /Zn \right) = - 0 . 76 V, {E^0}_\left( H^+ / H_2 \right) = 0 . 00 V\]

 


Standard hydrogen electrode operated under standard conditions of 1 atm Hpressure, 298 K, and pH = 0 has a cell potential of ____________.


Which cell will measure standard electrode potential of copper electrode?


The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called ______.


Use the data given in below find out which of the following is the strongest oxidising agent.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


Consider the figure and answer the following question.

If cell ‘A’ has ECell = 0.5V and cell ‘B’ has ECell = 1.1V then what will be the reactions at anode and cathode?


Represent the cell in which the following reaction takes place.The value of E˚ for the cell is 1.260 V. What is the value of Ecell?

\[\ce{2Al (s) + 3Cd^{2+} (0.1M) -> 3Cd (s) + 2Al^{3+} (0.01M)}\]


The standard electrode potential of the two half cells are given below:

\[\ce{Ni^{2+} + 2e^{-} -> Ni, E_0 = - 0.25 Volt}\]

\[\ce{Zn^{2+} + 2e^{-} -> Zn, E_0 = - 0.77 Volt}\]

The voltage of cell formed by combining the two half cells would be?


A voltaic cell is made by connecting two half cells represented by half equations below:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\], E0 = − 0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = + 0.77 V

Which statement is correct about this voltaic cell?


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