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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Out of o-nitrophenol and o-cresol which is more acidic? - Chemistry

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प्रश्न

Out of o-nitrophenol and o-cresol which is more acidic?

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उत्तर

There is an electron-withdrawing group NO2 that is present in the ortho position in ortho-nitrophenol which enhances the acidic strength and makes more acidic. In o-cresol there is an electron releasing group, they decrease acidic strength.

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पाठ 11: Alcohols, Phenols and Ethers - Multiple Choice Questions (Type - I) [पृष्ठ १५९]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 11 Alcohols, Phenols and Ethers
Multiple Choice Questions (Type - I) | Q 32 | पृष्ठ १५९

संबंधित प्रश्‍न

Give the structure of the product you would expect when the following alcohol reacts with HCl–ZnCl2.

Butan-1-ol


Account for the following:
o-nitrophenol is more steam volatile than p-nitrophenol.


Phenol is more acidic than alcohol because ____________.


The ionization constant of phenol is higher than that of ethanol because ____________.


In the following compounds:

The order of acidity is


In CH3CH2OH, the bond that undergoes heterolytical change most readily is ____________.


Phenol reacts with Br2 in CS2 at low temperature to give ____________.


Arrange the following in decreasing order of acidic character:


Which of the following statements is true:


Mark the correct order of decreasing acid strength of the following compounds.

(a)
(b)
(c)
(d)
(e)

Assertion: o-Nitrophenol is less soluble in water than the m- and p-isomers.

Reason: m- and p- Nitrophenols exist as associated molecules.


Which is the final product ‘A’ (major) in the given reaction?


In the following compounds:

(I) (II) (III) (IV)

The order to acidity is ______.


Which one of the following has the lowest pKa value?


For the pair phenol and cyclohexanol, answer the following:

Why is phenol more acidic than cyclohexanol?


Give the structure of the product you would expect when the following alcohol reacts with HBr.

2-Methylbutan-2-ol


Give the structure of the product you would expect when the following alcohol reacts with SOCl2.

Butan-1-ol


Give the structure of the product you would expect when the following alcohol reacts with SOCl2.

2-Methylbutan-2-ol


Compare acidity of phenol with that of ethanol.


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