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प्रश्न
How is impure copper purified by electrolysis ? Explain.
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उत्तर
Electrolytic refining is used for the purification of copper. In this case
Cathode : Pure copper strip
Anode : Impure copper
Electrolyte : A solution of copper sulphate and dilute sulphuric acid.
When the current is passed through the electrolyte , the copper ions of the copper sulphate solution are attracted to the cathode where they gain electrons and are deposited on pure copper strips. The impure copper loses electrons and passes into solution as soluble copper ions.
At Cathode : Cu+2 + 2e- → Cu
At anode : Cu + 2e- → Cu+2
APPEARS IN
संबंधित प्रश्न
Give one word or phrase for the following:
Electrolytic deposition of a superior metal on a baser metal.
State the electrode reaction at the anode during electrolysis of:
Aqueous copper sulphate solution.
The following question relate to the electroplating of an article with silver.
Name the electrode formed by the article which is to be plated.
The following question relate to the electroplating of an article with silver.
What should be the nature of the anode?
Element X is a metal with valency 2. Element Y is a non-metal with valency 3.
(a) Write equations to show how X and Y form ions.
(b) If Y is diatomic gas, write the equation for the direct combination of X and Y to form a compound.
(c) Write two applications of electrolysis in which anode diminish in mass.
(d) If the compound formed between X and Y is melted and an electric current passed through the molten compound, the element X will be obtained at the _____ and the Y at the ________of the electrolytic cell. (Provide the missing words).
Mr Ramu wants electrolyte his key chain with nickel to prevent rusting. For this electroplating
(i) Name the electrolyte
(ii) Name the cathode
(iii) Name the anode
(iv) Give the reaction at the cathode
(v) Give the reaction at the anode
Describe what happens to the iron object and the copper rod.
Write two applications of electrolysis in which the anode diminishes in mass.
What ions must be present in a solution used for electroplating a particular metal?
Electroplating steel objects with silver involves a three-step process.
Step 1: A coating of copper is applied to the object.
Step 2: A coating of nickel is applied to the object.
Step 3: The coating of silver is applied to the object.
-
- A diagram of the apparatus used for step 1 is shown
- The chemical process taking place on the surface of the object is \[\ce{Cu^2+(aq) + 2e- ->Cu(s)}\]
What is the observation seen on the surface of the object? - Explain why the concentration of copper ions in the electrolyte remains constant throughout step 1.
- The chemical process taking place on the surface of the object is \[\ce{Cu^2+(aq) + 2e- ->Cu(s)}\]
- A diagram of the apparatus used for step 1 is shown
- Give two changes which would be needed in order to coat nickel on to the object in step 2.
- Write down the reaction taking place at the positive electrode during step 3.
