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How Can You Determine Limiting Molar Conductivity,   0 M for Strong Electrolyte and Weak Electrolyte?

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प्रश्न

 How can you determine limiting molar conductivity,   0 m for strong electrolyte and weak electrolyte?

बेरीज
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उत्तर


For strong electrolyte, plot of m 
 against c, extrapolated to the y-axis, gives the value of m   for
strong electrolyte. For weak electrolyte, intercept is not obtained as o m 
 cannot be extra apolated to zero conc. hence limiting molar conductivity of weak electrolyte is obtained from that of strong electrolytes. Using Kohlrausch law of independent migration of ions.

`λ_m^0(CH_3COOH) = lamda^0CH_3COONa + lamda_{HCl}^circ - lamda_{NaCl}^circ`

`lamda_m^circ(CH_3COOH) = lamda_{CH_3COO-}^circ + lamda_{H^+}^circ`

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2018-2019 (March) 56/3/2

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