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प्रश्न
Haloalkanes react with alkalies to produce alcohol. Give the equation for the preparation of the second member of the homologous series of alcohol. State under what condition the reaction occurs.
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उत्तर
When ethyl halides are boiled with aqueous sodium hydroxide or potassium hydroxide, hydrolysis takes place with the formation of ethyl alcohol.
Condition: Alkyl halide is boiled with aqueous alkali.
\[\ce{C2H5Cl + NaOH -> \underset{Ethyl alcohol}{C2H5OH} + NaCl}\]
\[\ce{C2H5Br + KOH -> KBr + \underset{Ethyl alcohol}{C2H5OH}}\]
संबंधित प्रश्न
Write the molecular formula of two consecutive members of homologous series of aldehydes. State which part of these compounds determines their
- physical and
- chemical properties
Write the molecular formula of first two members of homologous series having functional group – OH
Fill in the following blank with suitable word:
Carbon compounds have usually ... melting points and boiling points because they are ...... in nature.
Give the molecular formula of one homologue of each of the following:
C2H6
Why homologous series of carbon compounds are so called? Write chemical formula of two consecutive members of a homologous series and state the part of these compounds that determines their (i) physical properties, and (ii) chemical properties.
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
Complete the following table for homologous series of Alkenes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Ethene | C2H4 | CH2 = CH2 | 2 | 0 | -102 |
| Propene | C3H6 | CH3–CH = CH2 | 3 | 1 | -48 |
| 1-Butene | C4H8 | CH3–CH2–CH = CH2 | ______ | ______ | -6.5 |
| 1-Pentene | C5H10 | CH3–CH2–CH2–CH = CH2 | ______ | ______ | 30 |
Consider the carbon compounds having following molecular formula:
(i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12
- State the number of double covalent bonds present in C3H6.
- Write the formula of first member of the homologous series to which the carbon compound C4H6 belongs.
- Which one of the above compounds forms a ring structure of carbon atoms?
- Identify, which of the above compounds, is a member of alkane series.
Name the third homologue of alcohols.
Name the third homologue of aldehydes.
