Advertisements
Advertisements
प्रश्न
Figure shows a cylindrical tube with adiabatic walls and fitted with a diathermic separator. The separator can be slid in the tube by an external mechanism. An ideal gas is injected into the two sides at equal pressures and equal temperatures. The separator remains in equilibrium at the middle. It is now slid to a position where it divides the tube in the ratio of 1:3. Find the ratio of the pressures in the two parts of the vessel.
Use R=8.314J K-1 mol-1
Advertisements
उत्तर
Since the separator initially divides the cylinder equally, the number of moles of gas are equal in the two parts. Thus,
n1 = n2= n
Volume of the first part = V
Volume of the second part =3V
It is given that the walls are diathermic. So, temperature of the two parts is equal. Thus,
T1 = T2 = T
Let pressure of first and second parts be P1 and P2, respectively.
For first part:- Applying equation of state, we get
\[ P_1 V = nRT ..........\left( 1 \right)\]
For second part:- Applying equation of state, we get
\[ P_2 \left( 3V \right) = nRT .............\left( 2 \right) \]
Dividing eq. (1) by eq. (2), we get
\[\frac{P_1 V}{P_2 \left( 3V \right)} = 1\]
\[ \Rightarrow \frac{P_1}{P_2} = \frac{3}{1}\]
\[ \Rightarrow P_1 : P_2 = 3: 1\]
APPEARS IN
संबंधित प्रश्न
Explain why cooking is faster in a pressure cooker.
A gas behaves more closely as an ideal gas at
Equal masses of air are sealed in two vessels, one of volume V0 and the other of volume 2V0. If the first vessel is maintained at a temperature 300 K and the other at 600 K, find the ratio of the pressures in the two vessels.
Use R = 8.31 JK-1 mol-1
An air bubble of radius 2.0 mm is formed at the bottom of a 3.3 m deep river. Calculate the radius of the bubble as it comes to the surface. Atmospheric pressure = 1.0 × 105 Pa and density of water = 1000 kg m−3.
Is a slow process always isothermal? Is a quick process always adiabatic?
In an adiabatic process on a gas with γ = 1.4, the pressure is increased by 0.5%. The volume decreases by about
A vessel of volume V0 contains an ideal gas at pressure p0 and temperature T. Gas is continuously pumped out of this vessel at a constant volume-rate dV/dt = r keeping the temperature constant. The pressure of the gas being taken out equals the pressure inside the vessel. Find (a) the pressure of the gas as a function of time, (b) the time taken before half the original gas is pumped out.
Use R = 8.3 J K−1 mol−1
A gas is enclosed in a cylindrical can fitted with a piston. The walls of the can and the piston are adiabatic. The initial pressure, volume and temperature of the gas are 100 kPa, 400 cm3 and 300 K, respectively. The ratio of the specific heat capacities of the gas, Cp / Cv = 1.5. Find the pressure and the temperature of the gas if it is (a) suddenly compressed (b) slowly compressed to 100 cm3.
The initial pressure and volume of a given mass of a gas (Cp/Cv = γ) are p0 and V0. The gas can exchange heat with the surrounding. (a) It is slowly compressed to a volume V0/2 and then suddenly compressed to V0/4. Find the final pressure. (b) If the gas is suddenly compressed from the volume V0 to V0/2 and then slowly compressed to V0/4, what will be the final pressure?
A barometer tube is 80 cm long (above the mercury reservoir). It reads 76 cm on a particular day. A small amount of water is introduced in the tube and the reading drops to 75.4 cm. Find the relative humidity in the space above the mercury column if the saturation vapour pressure at the room temperature is 1.0 cm.
The human body has an average temperature of 98°F. Assume that the vapour pressure of the blood in the veins behaves like that of pure water. Find the minimum atmospheric pressure which is necessary to prevent the blood from boiling. Use figure for the vapour pressures.
A faulty barometer contains certain amount of air and saturated water vapour. It reads 74.0 cm when the atmospheric pressure is 76.0 cm of mercury and reads 72.10 cm when the atmospheric pressure is 74.0 cm of mercury. Saturation vapour pressure at the air temperature = 1.0 cm of mercury. Find the length of the barometer tube above the mercury level in the reservoir.
On a winter day, the outside temperature is 0°C and relative humidity 40%. The air from outside comes into a room and is heated to 20°C. What is the relative humidity in the room? The saturation vapour pressure at 0°C is 4.6 mm of mercury and at 20°C it is 18 mm of mercury.
A bucket full of water is placed in a room at 15°C with initial relative humidity 40%. The volume of the room is 50 m3. (a) How much water will evaporate? (b) If the room temperature is increased by 5°C, how much more water will evaporate? The saturation vapour pressure of water at 15°C and 20°C are 1.6 kPa and 2.4 kPa respectively.
Use R = 8.3 J K-1 mol-1
A cuboidal container having dimensions 2 m × 1.5 m × 0.5 m holds a mixture of 12 g of He, 36 g of Ar, and 20 g of Ne, If the container is maintained at 300 K, Find the pressure exerted by the mixture (given MHe = 4, MAr = 40, MNe = 20).
If 1022 gas molecules each of mass 10-26 kg collide with a surface (perpendicular to it) elastically per second over an area of 1 m2 with a speed of 104 m/s, the pressure exerted by the gas molecules will be of the order of ______.
