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प्रश्न
Explain the term emulsion and types of emulsions.
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उत्तर
- A colloidal system in which one liquid is dispersed in another immiscible liquid is called an emulsion.
- There are liquid-liquid colloidal systems in which both liquids are either completely or partially immiscible.
- There are two types of emulsions:
- Emulsion of oil in water (o/w type):
An emulsion in which a dispersed phase is oil and the dispersion medium is water is called emulsion of oil in water.
Example:
1. Milk consists of particles of fat dispersed in water.
2. Other examples include vanishing cream, paint, etc. - Emulsion of water in oil (w/o type):
An emulsion in which the dispersed phase is water and dispersion medium is the oil is called emulsion of water in oil.
Example:
1. Cod liver oil consists of particles of water dispersed in oil.
2. Some other examples of this type include butter, cream, etc.
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संबंधित प्रश्न
Comment on the statement that “colloid is not a substance but a state of substance”.
Write one difference in Multimolecular colloid and Associated colloid
Choose the correct option.
The size of colloidal particles lies between ______.
Write Hardy-Sulze rules.
Write a note on Types of emulsion.
What are the applications of Electrophoresis?
Which type of colloid is formed on the dissolution of soap in water?
Which one of the following methods is used to make platinum sol?
Which of the following is multimolecular colloid?
Identify the CORRECT statements from the following.
i. The colour of colloidal dispersion depends on size of colloidal particles.
ii. Tyndall effect is used to distinguish between colloidal dispersion and true solution.
iii. Eosin and congo red are examples of negatively charged sols.
Mist is a colloidal solution of ____________.
In coagulation of positively charged ferric hydroxide sol, the most and least effective ions are ____________ and ____________ respectively.
Which of the following is an example of liquid-liquid system?
The order of coagulating power of following ions in the coagulation of a positive sol is:
i. \[\ce{PO^{3-}_4}\]
ii. \[\ce{SO^{2-}_4}\]
iii. \[\ce{[Fe(CN)6]^{4-}}\]
iv. \[\ce{NO^-_3}\]
Which of the following is NOT true for lyophilic colloids?
Tyndall effect is useful ______.
The movement of colloidal particles towards respective electrode under electric field is called ______.
In which of the following sols there is low affinity between dispersed phase and dispersion medium?
Some colloids are stable by their nature, i.e., gels, alloys, and solid foams. Gelatin and jellies are two common examples of a gel. The solid and liquid phases in a gel are interdispersed with both phases being continuous. In most systems, the major factor influencing the stability is the charge on the colloidal particles. If a particular ion is preferentially adsorbed on the surface of the particles, the particles in suspension will repel each other, thereby preventing the formation of aggregates that are larger than colloidal dimensions. The ion can be either positive or negative depending on the particular colloidal system, i.e., air bubbles accumulate negative ions, sulphur particles have a net negative charge in a sulphur sol, and the particles in a metal hydroxide sol are positively charged. Accumulation of charge on a surface is not an unusual phenomenon-dust is attracted to furniture surfaces by electrostatic forces. When salts are added to lyophobic colloidal systems the colloidal particles begin to form larger aggregates and a sediment forms as they settle. This phenomenon is called flocculation, and the suspension can be referred to as flocculated, or colloidally unstable. If the salt is removed, the suspension can usually be restored to its original state; this process is called deflocculation or peptization. The original and restored colloidal systems are called deflocculated, peptized, or stable sols.
Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
Gelatin is a _________ colloidal system.
Some colloids are stable by their nature, i.e., gels, alloys, and solid foams. Gelatin and jellies are two common examples of a gel. The solid and liquid phases in a gel are interdispersed with both phases being continuous. In most systems, the major factor influencing the stability is the charge on the colloidal particles. If a particular ion is preferentially adsorbed on the surface of the particles, the particles in suspension will repel each other, thereby preventing the formation of aggregates that are larger than colloidal dimensions. The ion can be either positive or negative depending on the particular colloidal system, i.e., air bubbles accumulate negative ions, sulphur particles have a net negative charge in a sulphur sol, and the particles in a metal hydroxide sol are positively charged. Accumulation of charge on a surface is not an unusual phenomenon-dust is attracted to furniture surfaces by electrostatic forces. When salts are added to lyophobic colloidal systems the colloidal particles begin to form larger aggregates and a sediment forms as they settle. This phenomenon is called flocculation, and the suspension can be referred to as flocculated, or colloidally unstable. If the salt is removed, the suspension can usually be restored to its original state; this process is called deflocculation or peptization. The original and restored colloidal systems are called deflocculated, peptized, or stable sols.
Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
Colloidal solutions are stable due to ______.
Which of the following process is responsible for the formation of delta at a place where rivers meet the sea?
How does the precipitation of colloidal smoke take place in Cottrell precipitator?
Why is \[\ce{Fe(OH)3}\] colloid positively charged, when prepared by adding \[\ce{FeCl3}\] to hot water?
Match the items of Column I and Column II.
| Column I | Column II |
| (i) Butter | (a) dispersion of liquid in liquid |
| (ii) Pumice stone | (b) dispersion of solid in liquid |
| (iii) Milk | (c) dispersion of gas in solid |
| (iv) Paints | (d) dispersion of liquid in solid |
Which of the following substances will precipitate the negatively charge emulsion
Van Arkel's method of purification of metals involves converting the metal to a ______.
Identify the correct decreasing order of precipitation power of flocculating ion added, from following.
