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प्रश्न
Explain the deviation in ionisation enthalpy of some elements from the general trend by using the given figure.
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उत्तर
The deviation in the ionization enthalpy of some elements from the general trend can be explained by the points as given below:-
(i) The fully filled and half-filled orbital provide extra stability due to the symmetry.
(ii) The effective nuclear charge.
(iii) The \[\ce{e- - e-}\] repulsion which lead to instability.
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संबंधित प्रश्न
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Hint: Apply the idea of mole concept to derive the answer.
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order Li < B < Be < C < O < N < F < Ne.
Explain why Be has higher ΔiH than B?
Among the second period elements the actual ionization enthalpies are in the
order Li < B < Be < C < O < N < F < Ne.
Explain why O has lower ΔiH than N and F?
How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
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| B | Al | Ga | In | Tl |
| 801 | 577 | 579 | 558 | 589 |
How would you explain this deviation from the general trend?
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Reason (R): When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.
Define ionisation enthalpy. Discuss the factors affecting ionisation enthalpy of the elements and its trends in the periodic table.
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Arrange the following elements in increasing order of first ionization enthalpy:
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Choose the correct answer from the options given below:
