Advertisements
Advertisements
प्रश्न
Arrange the elements \[\ce{N, P, O}\] and \[\ce{S}\] in the order of increasing first ionisation enthalpy. Give reason for the arrangement assigned.
Advertisements
उत्तर
\[\ce{S < P < O < N}\]
Ionisation enthalpy increases from left to right in a period and decreases down the group. N has higher ionisation enthalpy than \[\ce{O}\] due to extra stability of half-filled orbitals. Similarly, \[\ce{P}\] has higher ionisation enthalpy than S due to half-filled orbitals.
APPEARS IN
संबंधित प्रश्न
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Hint: Apply the idea of mole concept to derive the answer.
Among the second period elements the actual ionization enthalpies are in the
order Li < B < Be < C < O < N < F < Ne.
Explain why Be has higher ΔiH than B?
Among the second period elements the actual ionization enthalpies are in the
order Li < B < Be < C < O < N < F < Ne.
Explain why O has lower ΔiH than N and F?
What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?
The first ionization enthalpy values (in kJmol–1) of group 13 elements are:-
| B | Al | Ga | In | Tl |
| 801 | 577 | 579 | 558 | 589 |
How would you explain this deviation from the general trend?
Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer.
Which one of the following statements is incorrect in relation to ionization enthalpy?
Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Explain.
Explain the deviation in ionisation enthalpy of some elements from the general trend by using the given figure.
Define ionisation enthalpy. Discuss the factors affecting ionisation enthalpy of the elements and its trends in the periodic table.
Consider the elements Mg, Al, S, P and Si, the correct increasing order of their first ionization enthalpy is ______.
For the gaseous reaction, \[\ce{K_{(g)} + F_{(g)} -> K^+_{ (g)} + F^-_{ (g)}}\], ΔH was calculated to be 19 kcal/mol under conditions where the cations and anions were prevented by electrostatic separation from combining with each other. The ionisation energy of K is 4.3 eV. The electron affinity of F is ______. (in eV)
`"A"_0/2` atoms of X(g) are converted into X+(g) by absorbing energy E1. `"A"_0/2` ions of X+(g) are converted into X−(g) with release of energy E2. Hence ionization energy and electron affinity of X(g) are ______.
The decreasing order of the second ionization potential of K, Ca and Ba is ______.
Which of the following atoms has the highest first ionization energy?
