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Arrange the elements N,P,O and S in the order of increasing first ionisation enthalpy. Give reason for the arrangement assigned.

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प्रश्न

Arrange the elements \[\ce{N, P, O}\] and \[\ce{S}\] in the order of increasing first ionisation enthalpy. Give reason for the arrangement assigned.

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उत्तर

\[\ce{S < P < O < N}\]

Ionisation enthalpy increases from left to right in a period and decreases down the group. N has higher ionisation enthalpy than \[\ce{O}\] due to extra stability of half-filled orbitals. Similarly, \[\ce{P}\] has higher ionisation enthalpy than S due to half-filled orbitals.

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पाठ 3: Classification of Elements and Periodicity in Properties - Multiple Choice Questions (Type - I) [पृष्ठ ३३]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 3 Classification of Elements and Periodicity in Properties
Multiple Choice Questions (Type - I) | Q 37.(i) | पृष्ठ ३३

संबंधित प्रश्‍न

Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Hint: Apply the idea of mole concept to derive the answer.


Among the second period elements the actual ionization enthalpies are in the

order Li < B < Be < C < O < N < F < Ne.

Explain why Be has higher ΔiH than B?


Among the second period elements the actual ionization enthalpies are in the

order Li < B < Be < C < O < N < F < Ne.

Explain why O has lower ΔiH than N and F?


How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?


The first ionization enthalpy values (in kJmol–1) of group 13 elements are:-

B Al Ga In Tl
801 577 579 558 589

How would you explain this deviation from the general trend?


Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer.


Which one of the following statements is incorrect in relation to ionization enthalpy?


Among the elements \[\ce{B, Al, C}\] and \[\ce{Si}\], which element has the highest first ionisation enthalpy? 


Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Explain.


Assertion (A): Generally, ionisation enthalpy increases from left to right in a period.

Reason (R): When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.


Define ionisation enthalpy. Discuss the factors affecting ionisation enthalpy of the elements and its trends in the periodic table.


In general, the property (magnitudes only) that shows an opposite trend in comparison to other properties across a period is ______. 


Consider the elements Mg, Al, S, P and Si, the correct increasing order of their first ionization enthalpy is ______.


For the gaseous reaction, \[\ce{K_{(g)} + F_{(g)} -> K^+_{ (g)} + F^-_{ (g)}}\], ΔH was calculated to be 19 kcal/mol under conditions where the cations and anions were prevented by electrostatic separation from combining with each other. The ionisation energy of K is 4.3 eV. The electron affinity of F is ______. (in eV)


Arrange the following elements in increasing order of first ionization enthalpy:

Li, Be, B, C, N

Choose the correct answer from the options given below:


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