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प्रश्न
Assertion (A): Generally, ionisation enthalpy increases from left to right in a period.
Reason (R): When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.
पर्याय
Assertion is correct statement and reason is wrong statement.
Assertion and reason both are correct statements and reason is correct explanation of assertion.
Assertion and reason both are wrong statements.
Assertion is wrong statement and reason is correct statement.
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उत्तर
Assertion and reason both are correct statements and reason is correct explanation of assertion.
Explanation:
Ionisation enthalpy increases from left to right across the period due to decrease in atomic size. The electrons present within the subshell has almost same effective nuclear charge.
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संबंधित प्रश्न
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Hint: Apply the idea of mole concept to derive the answer.
Among the second period elements the actual ionization enthalpies are in the
order Li < B < Be < C < O < N < F < Ne.
Explain why Be has higher ΔiH than B?
Among the second period elements the actual ionization enthalpies are in the
order Li < B < Be < C < O < N < F < Ne.
Explain why O has lower ΔiH than N and F?
What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?
The first ionization enthalpy values (in kJmol–1) of group 13 elements are:-
| B | Al | Ga | In | Tl |
| 801 | 577 | 579 | 558 | 589 |
How would you explain this deviation from the general trend?
Which one of the following statements is incorrect in relation to ionization enthalpy?
Among the elements \[\ce{B, Al, C}\] and \[\ce{Si}\], which element has the highest first ionisation enthalpy?
Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Explain.
Arrange the elements \[\ce{N, P, O}\] and \[\ce{S}\] in the order of increasing first ionisation enthalpy. Give reason for the arrangement assigned.
Explain the deviation in ionisation enthalpy of some elements from the general trend by using the given figure.

Explain the following:
Ionisation enthalpy decrease in a group from top to bottom?
Discuss and compare the trend in ionisation enthalpy of the elements of group1 with those of group17 elements.
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