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Answer the following in brief. How will you determine activation energy graphically using the Arrhenius equation? - Chemistry

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प्रश्न

Answer the following in brief.

How will you determine activation energy graphically using the Arrhenius equation?

थोडक्यात उत्तर
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उत्तर

Graphical representation of activation energy

Arrhenius equation is `"k" = "Ae"^((-"E"_"a")/("RT"))`

Taking the logarithm of both sides of Eqn. we obtain

In k = -`"E"_"a"/"RT" + "In A"`

Converting the natural base to base 10 we write

This equation is of the form of straight-line y = mx + c.

The Arrhenius plot of log10k versus `1/"T"` gives a straight line as shown in the diagram. A slope of the line is `-"E"_"a"/(2.303 "R")` with its intercept being log10A.

From a slope of the line, the activation energy can be determined.

Variation of log10k with 1/T

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Temperature Dependence of Reaction Rates
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पाठ 6: Chemical Kinetics - Exercises [पृष्ठ १३७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 6 Chemical Kinetics
Exercises | Q 3. xiv. (a) | पृष्ठ १३७

संबंधित प्रश्‍न

Answer the following in one or two sentences.

Write the Arrhenius equation and explain the terms involved in it.


Explain with the help of the Arrhenius equation, how do the rate of reaction changes with temperature.


Answer the following in brief.

Explain graphically the effect of temperature on the rate of reaction.


Solve

The energy of activation for a first-order reaction is 104 kJ/mol. The rate constant at 25°C is 3.7 × 10–5 s –1. What is the rate constant at 30°C? (R = 8.314 J/K mol)


The rate constant for the first-order reaction is given by log10 k = 14.34 – 1.25 × 104 T. Calculate activation energy of the reaction.


Solve

What fraction of molecules in a gas at 300 K collide with an energy equal to the activation energy of 50 kJ/mol?


How will you determine activation energy from rate constants at two different temperatures?


Explain with the help of the Arrhenius equation, how do the rate of reaction changes with activation energy.


A catalyst lowers the activation energy of a certain reaction from 83.314 to 75 kJ mol−1 at 500 K. What will be the rate of reaction as compared to uncatalysed reaction? Assume other things are equal.


Which among the following equation represents Arrhenius equation?


Slope of the straight line obtained by plotting log10k against represents what term?


Write the mathematical equation between reaction rate constant and its activation energy.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with activation energy.


Explain, with the help of the Arrhenius equation, how does the rate of reaction changes with temperature.


Explain, with the help of the Arrhenius equation, how does the rate of reaction changes with activation energy.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with activation energy.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with activation energy.


Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.


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