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Answer in brief. What is the standard enthalpy of combustion? Give an example.

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प्रश्न

Answer in brief.

What is the standard enthalpy of combustion? Give an example.

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उत्तर

  1. The standard enthalpy of combustion of a substance is the standard enthalpy change accompanying a reaction in which one mole of the substance in its standard state is completely oxidised.
  2. Consider the reaction,
    C2H2(g) + `5/2` O2(g) → 2CO2(g) + H2O(l), Δr H° = - 1300 kJ 
    In the above reaction, the standard enthalpy change of the oxidation reaction, –1300 kJ is the standard enthalpy of combustion of C2H2(g).
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पाठ 4: Chemical Thermodynamics - Exercises [पृष्ठ ८७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 4 Chemical Thermodynamics
Exercises | Q 3.4 | पृष्ठ ८७

संबंधित प्रश्‍न

Select the most appropriate option.

Which of the following reactions is exothermic?


Answer in brief.

How will you calculate reaction enthalpy from data on bond enthalpies?


Answer in brief.

How much heat is evolved when 12 g of CO reacts with NO2? The reaction is:

4CO(g)  2NO2(g) → 4CO2(g) + N2(g), ΔrH° = - 1200 kJ


The enthalpy change for the reaction, \[\ce{C2H4_{(g)} + H2_{(g)} -> C2H6_{(g)}}\] is −620 J when 100 mL of ethylene and 100 ml of \[\ce{H2}\] react at 1 bar pressure. Calculate the pressure volume type of work and ΔU for the reaction.


The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water.


Calculate enthalpy of formation of HCl if bond enthalpies of H2, Cl2 and HCl are 434 kJ mol-1, 242 kJ mol–1 and 431 kJ mol–1 respectively.


Calculate the standard enthalpy of combustion of CH4(g) if ΔfH°(CH4) = – 74.8 kJ mol–1, ΔfH°(CO2) = – 393.5 kJ mol–1 and ΔfH°(H2O) = – 285.8 kJ mol–1.


Define the Bond enthalpy.


Calculate the standard enthalpy of the reaction.

\[\ce{2Fe_{(s)} + \frac{3}{2} O_{2(g)} -> Fe2O_{3(s)}}\]

Given:

1. \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], rH° = –847.6 kJ
2. \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], rH° = –1670 kJ

Define the Enthalpy of ionisation.


When 2 moles of C2H6(g) are completely burnt, 3129 kJ of heat is liberated. If ∆Hf for CO2(g) and H2O(l) are −395 and −286 kJ per mole respectively, the heat combustion of C2H6(g) is ____________.


The standard heats of formation for CCl4(g), H2O(g), CO2(g), and HCl(g) are −25.5, −57.8, −94.1 and −22.1 kcal mol−1, respectively.

∆H for the reaction

\[\ce{CCl4_{(g)} + 2H2O_{(g)} -> CO2_{(g)} + 4HCl_{(g)}}\] at 298 K


The enthalpy change accompanying a reaction in which 1 mole of the substance in the standard state reacts completely with oxygen or is completely burnt is called as ____________.


\[\ce{S + 3/2O2 -> SO3 +2{x} kcal}\] .........(i)

\[\ce{SO2 + 1/2O2 -> SO3 + {y} kcal}\] .......(ii)

The heat of formation of SO2 is ____________.


The heat evolved in the combustion of benzene is given by

\[\ce{C6H6 + 7 1/2O2 -> 6CO2_{(g)} + 3H2O_{(l)}}\]; ΔH = −3264.6 kJ

Which of the following quantities of heat energy will be evolved when 39 g C6H6 are burnt?


Given the reaction,

\[\ce{CH2O_{(g)} + O2_{(g)} -> CO2_{(g)} + H2O_{(g)}}\] ΔH = −527 kJ

How much heat will be evolved in the formation of 60 g of CO2?


Combustion of glucose takes place as

\[\ce{C6H12O6_{(s)} + 6O2_{(g)} -> 6CO2_{(g)} + 6H2O_{(g)}}\]; ΔH = −72 kcal mol−1

The energy needed for the production of 1.8 g of glucose by photosynthesis will be ___________.


Standard enthalpy of formation of water is - 286 kJ mol-1. When 1800 mg of water is formed from its constituent elements in their standard states the amount of energy liberated is ______.


Given that,

\[\ce{C_{(s)} + O_{2(g)} -> CO_{2(g)}}\]   ΔH° = -X kJ

\[\ce{2CO_{(g)} + O_{2(g)} -> 2CO_{2(g)}}\]   ΔH° = - Y kJ, then standard enthalpy of formation of carbon monoxide is ________.


Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?


Which of the following equations has ΔfH° and ΔH° same?


Heat of formation of ethane, ethylene acetylene and carbon dioxide are - 136, - 66, - 228 and - 395 (all in kJ) respectively, most stable among them is ______.


Calculate the standard enthalpy of formation of CH3OH(l) from the following data:

  1. \[\ce{CH3OH_{(l)} + 3/2 O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)}ΔH^° = - 726 kJ mol^{-1}}\]
  2. \[\ce{C_{(s)} + O2_{(g)} → CO2_{(g)}Δ_cH^° = – 393 kJ mol^{-1}}\]
  3. \[\ce{H2_{(g)} + 1/2 O2_{(g)} -> H2O_{(l)}Δ_fH^° = - 286 kJ mol^{-1}}\]

What is the amount of water formed by the combustion of 1.6 g methane?


When 0.5 gram of sulphur is burnt to form SO2, 4.6 kJ of heat liberated. Calculate enthalpy of formation of SO2(g). (Atomic mass : S = 32, O = 16)


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[CH3CHO(l)] = - 1166 kJ mol-1


Calculate heat evolved for combustion of 13 gm of acetylene (C2H2).

Given: \[\ce{C2H2_{(g)} + 5/2O_{2(g)}-> 2CO_{2(g)} + H2O_{(l)} \Delta_{(c)}H^{0} = - 1300 kJ}\]


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