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Tamil Nadu Board of Secondary EducationHSC Science कक्षा १२

HSC Science कक्षा १२ - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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The decomposition of phosphine (PH3) on tungsten at low pressure is a first-order reaction. It is because the

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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This reaction follows first-order kinetics. The rate constant at particular temperature is 2.303 × 10−2 hour−1. The initial concentration of cyclopropane is 0.25 M. What will be the concentration of cyclopropane after 1806 minutes? (log 2 = 0.3010)

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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For a first-order reaction, the rate constant is 6.909 min−1 the time taken for 75% conversion in minutes is

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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In a first order reaction \[\ce{x -> y}\]; if k is the rate constant and the initial concentration of the reactant x is 0.1 M, then, the half life is

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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Assertion: rate of reaction doubles when the concentration of the reactant is doubles if it is a first-order reaction.

Reason: rate constant also doubles.

[7] Chemical Kinetics
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The rate constant of a reaction is 5.8 × 10−2 s−1. The order of the reaction is ____________.

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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If 75% of a first order reaction was completed in 60 minutes, 50% of the same reaction under the same conditions would be completed in ____________.

[7] Chemical Kinetics
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Describe the graphical representation of first order reaction.

[7] Chemical Kinetics
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Write the rate law for the following reaction.

A reaction that is `3/2` order in x and zero order in y.

[7] Chemical Kinetics
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Write the rate law for the following reaction.

A reaction that is second order in NO and first order in Br2.

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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Give two examples for zero order reaction.

[7] Chemical Kinetics
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Identify the order for the following reaction.

Radioactive disintegration of 92U238

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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The time for half change in a first order decomposition of a substance A is 60 seconds. Calculate the rate constant. How much of A will be left after 180 seconds?

[7] Chemical Kinetics
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A zero order reaction is 20% complete in 20 minutes. Calculate the value of the rate constant. In what time will the reaction be 80% complete?

[7] Chemical Kinetics
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From the following data, show that the decomposition of hydrogen peroxide is a reaction of the first order:

t (min) 0 10 20
V (ml) 46.1 29.8 19.3

Where t is the time in minutes and V is the volume of standard KMnO4 solution required for titrating the same volume of the reaction mixture.

[7] Chemical Kinetics
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A first order reaction is 40% complete in 50 minutes. Calculate the value of the rate constant. In what time will the reaction be 80% complete?

[7] Chemical Kinetics
Chapter: [7] Chemical Kinetics
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Define the ionic product of water. Give its value at room temperature.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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How many faradays of electricity are required for the following reaction to occur

\[\ce{MnO^-_4 -> Mn^2+}\]

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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A current strength of 3.86 A was passed through molten Calcium oxide for 41minutes and 40 seconds. The mass of Calcium in grams deposited at the cathode is (atomic mass of Ca is 40g/mol and 1F = 96500 C).

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because ____________.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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