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Explain the nature of zinc oxide with the help of the reactions.
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Absolute entropies of solids, liquids and gases can be determined by
- Measuring heat capacity of substance at various temperatures
- Subtracting standard entropy of reactants from products
- Measuring vibrational motion of molecules
- Using formula ΔS° = ST° - SO°
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The determination of molar mass from elevation in boiling point is called as
- cryoscopy
- colorimetry
- ebullioscopy
- spectroscopy
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How is propene converted into 1- bromopropane and 2 - bromopropane?
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The preparation of alkyl fluoride from alkyl chloride, in presence of metallic fluorides is known as ______________.
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Colligative property depends only on ........................ in a solution.
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Draw neat and labelled diagram of dry cell.
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Determine whether the reactions with the following ΔH and ΔS values are spontaneous or non-spontaneous. State whether the reactions are exothermic or endothermic.
(a) ΔH = -110kJ, ΔS = + 40JK-1 at 400 K
(b) ΔH = + 40kJ, ΔS = -120JK-1 at 250K
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Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law with `t_(1/2)` = 3 hours. What fraction of the sample of sucrose remains after 8 hours?
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Niobium crystallises as body centred cube (BCC) and has density of 8.55 Kg / dm-3 . Calculate the attomic radius of niobium.
(Given : Atomic mass of niobium = 93).
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What is the geometry of chromate ion?
- Tetrahedral
- Octahedral
- Trigonal planer
- Linear
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Identify the strongest acid amongst the followings:
- Chloroacetic acid
- Acetic acid
- Trichloroacetic acid
- Dichloroaceticacid
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Write a note on Friedel Craft’s acylation.
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Explain, why are boiling points of carboxylic acids higher than corresponding alcohols
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A solution of glucose in water is labelled as 10% (W/W).
Calculate:
a. Molality
b. Molarity of the solution.
[Given: Density of solution is 1.20 g mL-1 and molar mass of glucose is 180 g mol-1 ]
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Write ‘four’ uses of hydrochloric acid.
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What is the molecular formula of chromyl chloride?
(A) CrO2Cl2
(B) CrOCl2
(C) CrCl3
(D) Cr2OCl2
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A solution containing 0.73 g of camphor (molar mass 152 g . mol-1) in 36.8 g of acetone (boiling point 56.3°C) boils at 56.55°C. A solution of 0.564 g of unknown compound in the same weight of acetone boils at 56.46oC. Calculate the molar mass of the unknown compound.
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What is the action of acidified potassium dichromate on - SO2
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Draw structure of dichromate ion
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