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HSC Science (General) १२ वीं कक्षा - Maharashtra State Board Question Bank Solutions for Chemistry

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Chemistry
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What is natural rubber?

(A) Cis-1,4-polyisoprene

(B) Neoprene

(C) Trans-1,4-polyisoprene

(D) Butyl rubber

[15] Polymers
Chapter: [15] Polymers
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What is the value of for the following reaction at 298 K -

6CO2+ 6H20(l) → C6H1206(s) + 602(g),

Given that: ΔG° = 2879 kj mol-1, AS = -210 JK-1 mol-1.

[4] Electrochemistry
Chapter: [4] Electrochemistry
Concept: undefined >> undefined

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State and explain Hess’s law of constant heat summation.

[3] Chemical Thermodynamics and Energetic
Chapter: [3] Chemical Thermodynamics and Energetic
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With the help of the equation ΔG° = - nFEocell. Explain that cell potential is an intensive property.

[4] Electrochemistry
Chapter: [4] Electrochemistry
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Define van’t Hoff factor.

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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A unit cell of iron crystal has edge length 288 pm and density 7.86 g.cm-3. Find the number of atoms per unit cell and type of the crystal lattice.

Given : Molar mass of iron = 56 g.mol-1; Avogadro's number NA = 6.022 x 1023.

[1] Solid State
Chapter: [1] Solid State
Concept: undefined >> undefined

Mohr’s Salt is -

(a) Ferrous ammonium sulphate

(b) Ferrous sulphate

(c) Ammonium sulphate

(d) Ferric sulphate

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
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How many atoms constitute one unit cell of a face-centered cubic crystal?

[1] Solid State
Chapter: [1] Solid State
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Gold occurs as face centred cube and has a density of 19.30 kg dm-3. Calculate atomic radius of gold. (Molar mass of Au = 197)

[1] Solid State
Chapter: [1] Solid State
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What are hormones?

[14.02] Proteins
Chapter: [14.02] Proteins
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Define complex lipids

[14.02] Proteins
Chapter: [14.02] Proteins
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Face centred cubic crystal lattice of copper has density of 8.966 g.cm-3. Calculate the volume of the unit cell. Given molar mass of copper is 63.5 g mol-1 and Avogadro number Nis 6.022 x 1023 mol-1

[1] Solid State
Chapter: [1] Solid State
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Write a note on the self oxidation-reduction reaction of an aldehyde with a suitable example.

[12.01] Aldehydes and Ketones
Chapter: [12.01] Aldehydes and Ketones
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Write names and chemical formulae of monomers used in preparing Buna-S.

[15] Polymers
Chapter: [15] Polymers
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Mention 'two' functions of lipids

[14.02] Proteins
Chapter: [14.02] Proteins
Concept: undefined >> undefined

An element crystallises in a b.c.c lattice with cell edge of 500 pm. The density of the element is 7.5g cm-3. How many atoms are present in 300 g of the element?

[1] Solid State
Chapter: [1] Solid State
Concept: undefined >> undefined

Following reactions occur at cathode during the electrolysis of aqueous silver chloride solution :

`Ag^+(aq)+e^(-)rarrAg(s)" ""      ""       "E^@=+0.80V`

`H^+(aq)+e^(-)rarr1/2H_2(g)" "" "" " E^@=0.00V`

On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?

[4] Electrochemistry
Chapter: [4] Electrochemistry
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3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van't Hoff factor and predict the nature of solute (associated or dissociated).

(Given : Molar mass of benzoic acid = 122 g mol−1, Kf for benzene = 4.9 K kg mol−1)

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
Concept: undefined >> undefined

An element with molar mass 27 g mol−1 forms a cubic unit cell with edge length 4.05 ✕ 10−8 cm. If its density is 2.7 g cm−3, what is the nature of the cubic unit cell?

[1] Solid State
Chapter: [1] Solid State
Concept: undefined >> undefined

Calculate ΔrG° for the reaction 

Mg (s) + Cu2+ (aq) → Mg2+ (aq) + Cu (s)

Given : E°cell = + 2.71 V, 1 F = 96500 C mol–1

[4] Electrochemistry
Chapter: [4] Electrochemistry
Concept: undefined >> undefined
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