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Define van’t Hoff factor. - Chemistry

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प्रश्न

Define van’t Hoff factor.

परिभाषा
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उत्तर

The ratio of the observed (experimental) value of a colligative property to the normal (calculated) value of the same property is termed as van’t Hoff factor, i.

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अध्याय 2: Solutions - VERY SHORT ANSWER TYPE QUESTIONS [पृष्ठ ११०]

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नूतन Chemistry Part 1 and 2 [English] Class 12 ISC
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संबंधित प्रश्न

Derive van’t Hoff general solution equation.


The substance ‘X’, when dissolved in solvent water gave molar mass corresponding to the molecular formula ‘X3’. The van’t Hoff factor (i) is _______.

(A) 3

(B) 0.33

(C) 1.3

(D) 1


Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in methanol.


19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is 1.0°C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid.


Define the term Abnormal molar mass


How van’t Hoff factor is related to the degree of dissociation?


Give reasons for the following

Elevation of the boiling point of 1 M KCl solution is nearly double than that of 1 M sugar solution.


The Van't Hoff factor (i) for a dilute aqueous solution of the strong elecrolyte barium hydroxide is (NEET) ______.


The freezing point depression constant for water is 1.86° K Kg mol-1. If 5 g Na2SO4 is dissolved in 45 g water, the depression in freezing point is 3.64°C. The Vant Hoff factor for Na2SO4 is ______.


The van’t Hoff factor (i) accounts for ____________.


We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1 M, 0.01 M and 0.001 M, respectively. The value of van’t Hoff factor for these solutions will be in the order ______.


Van’t Hoff factor i is given by the expression:

(i)  i = `"Normal molar mass"/"Abnormal molar mass"`

(ii)  i = `"Abnormal molar mass"/"Normal molar mass"`

(iii) i = `"Observed colligative property"/"Calculated colligative property"`

(iv) i =  `"Calculated colligative property"/"Observed colligative property"`


Van't Hoff factor I is given by expression.


Maximum lowering of vapour pressure is observed in the case of ______.


Geraniol, a volatile organic compound, is a component of rose oil. The density of the vapour is 0.46 g L–1 at 257°C and 100 mm Hg. The molar mass of geraniol is ______ g mol–1. (Nearest Integer)

[Given: R = 0.082 L atm K–1 mol–1]


When 9.45 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by 0.5°C. The dissociation constant of ClCH2COOH is x × 10−3. The value of x is ______. (Rounded-off to the nearest integer)

[\[\ce{K_{f(H_2O)}}\] = 1.86 K kg mol−1]


The degree of dissociation of Ca(NO3)2 in a dilute aqueous solution containing 7 g of the salt per 100 g of water at 100°C is 70%. If the vapour pressure of water at 100°C is 760 mm. The vapour pressure of the solution is ______ mm.


Consider the reaction

\[\begin{bmatrix}\begin{array}{cc}
\phantom{.......}\ce{CH3}\\
\phantom{....}|\\
\ce{CH3CH2CH2 - \overset{⊕}{N} - CH2CH3}\\
\phantom{....}|\\
\phantom{.......}\ce{CH3}
\end{array}\end{bmatrix}\]\[\ce{OH^- ->[Heat] ?}\]

Which of the following is formed in a major amount?


When 19.5 g of F – CH2 – COOH (Molar mass = 78 g mol−1), is dissolved in 500 g of water, the depression in freezing point is observed to be 1°C. Calculate the degree of dissociation of F – CH2 – COOH.

[Given: Kf for water = 1.86 K kg mol−1]


Why is the value of van't Hoff factor for ethanoic acid in benzene close to 0.5?


Why is boiling point of 1 M NaCl solution more than that of 1 M glucose solution?


Calculate Van't Hoff factor for an aqueous solution of K3 [Fe(CN)6] if the degree of dissociation (α) is 0.852. What will be boiling point of this solution if its concentration is 1 molal? (Kb = 0.52 K kg/mol)


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