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What are the high-spin complexes?
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[CoCl4]2− is a tetrahedral complex. Draw its box orbital diagram. State which orbitals participate in hybridization.
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[CoCl4]2- is a tetrahedral complex. Draw its box orbital diagram. State which orbitals participate in hybridization.
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What are strong field and weak field ligands ? Give one example of each.
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With the help of the crystal field, the energy-level diagram explains why the complex [Cr(en)3]3⊕ is coloured.
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Give valence bond description for the bonding in the complex [VCl4]-. Draw box diagrams for the free metal ion. Which hybrid orbitals are used by the metal? State the number of unpaired electrons.
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Draw a qualitatively energy-level diagram showing d-orbital splitting in the octahedral environment. Predict the number of unpaired electrons in the complex [Fe(CN)6]4-. Is the complex diamagnetic or paramagnetic? Is it coloured? Explain.
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Formic acid is stronger than acetic acid. Explain.
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Arrange the following carboxylic acids with increasing order of their acidic strength and justify your answer.
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Write a reaction to convert Aniline into p-bromoaniline.
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Complete the following reaction :
\[\ce{C6H5NH2 + Br2_{(aq)} -> ?}\]
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Write a reaction to bring about the following conversions: Aniline into p-nitroaniline
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Write a reaction to bring about the following conversions: Aniline into sulphanilic acid?
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How nanotechnology plays an important role in water purification techniques?
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Which flower is an example of self-cleaning?
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Explain, why [Co(NH3)6]3+ ion is low spin? Calculate number of unpaired electrons and write the geometry of [Co(NH3)6]3+.
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Answer the following with respect to [CoF6]3– ion
- Type of hybridization
- Number of unpaired electrons
- Geometry of complex ion
- Magnetic property
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Freezing point depression constant of a solvent is _______.
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Write the effect of dissolution of a nonvolatile solute on the freezing point of solvent.
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