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Explain giving reason:
Transition metals and many of their compounds show paramagnetic behaviour.
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Write down the electronic configuration of Cr3+.
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Write down the electronic configuration of Pm3+.
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Write down the electronic configuration of Cu+.
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Write down the electronic configuration of Ce4+.
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Write down the electronic configuration of Co2+.
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Write down the electronic configuration of Lu2+.
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Write down the electronic configuration of Mn2+.
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Write down the electronic configuration of Th4+.
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Explain the following, giving two examples:
Coordination entity
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What is meant by unidentate ligand?
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What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H2S(g) is passed through this solution?
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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
K3[Co(C2O4)3]
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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[CrCl2(en)2]Cl
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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
(NH4)2[CoF4]
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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
[Mn(H2O)6]SO4
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Amongst the following, the most stable complex is:
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Identify the monomer in the following polymeric structures.

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How do you explain the absence of the aldehyde group in the pentaacetate of D-glucose?
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Classify the following amine as primary, secondary or tertiary:
(C2H5)2NH
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