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Predict the product of reaction of aniline with bromine in non-polar solvent such as \[\ce{CS2}\].
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Why is aniline soluble in aqueous HCl?
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How will you carry out the following conversions?
toluene `->` p-toluidine
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How will you carry out the following conversions?
p-toluidine diazonium chloride `→` p-toluic acid
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Match the compounds given in Column I with the items given in Column II.
| Column I | Column II | ||
| (i) | Benzene sulphonyl chloride | (a) | Zwitter ion |
| (ii) | Sulphanilic acid | (b) | Hinsberg reagent |
| (iii) | Alkyl diazonium salts | (c) | Dyes |
| (iv) | Aryl diazonium salts | (d) | Conversion to alcohols |
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A colourless substance ‘A’ \[\ce{(C6H7N)}\] is sparingly soluble in water and gives a water soluble compound ‘B’ on treating with mineral acid. On reacting with \[\ce{CHCl3}\] and alcoholic potash ‘A’ produces an obnoxious smell due to the formation of compound ‘C’. Reaction of ‘A’ with benzenesulphonyl chloride gives compound ‘D’ which is soluble in alkali. With \[\ce{NaNO2}\] and \[\ce{HCl}\], ‘A’ forms compound ‘E’ which reacts with phenol in alkaline medium to give an orange dye ‘F’. Identify compounds ‘A’ to ‘F’.
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Predict the reagent or the product in the following reaction sequence.

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Discuss briefly, giving an example of the role of coordination compounds in biological systems.
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Account for the following:
Ti(IV) is more stable than the Ti (II) or Ti(III).
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Draw the structures of the given compound - 3-Bromo-4-phenylpentanoic acid
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What is meant by the chelate effect? Give an example.
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Draw the structure of the following compound.
3-Bromo-4-phenylpentanoic acid
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What is meant by the chelate effect? Give an example.
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Draw the structure of the following compound.
3-Bromo-4-phenylpentanoic acid
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What is meant by the chelate effect? Give an example.
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What is meant by the chelate effect? Give an example.
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Draw the structure of the given compound.
3-Bromo-4-phenylpentanoic acid
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What is meant by the chelate effect? Give an example.
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Discuss briefly, giving an example of the role of coordination compounds in analytical chemistry.
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Discuss briefly, giving an example of the role of coordination compounds in extraction/metallurgy of metals.
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