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How would you account for the following:
Actinoid contraction is greater than lanthanoid contraction.
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Give reasons : n-Butyl bromide has higher boiling point than t-butyl bromide.
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Write the structures of main products when aniline reacts with the following reagents : HCl
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Write the chemical equations involved when aniline is treated with the following reagents: HCI
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Give reasons for the following : Phenol is more acidic than ethanol.
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Give reasons for the following : Boiling point of ethanol is higher in comparison to methoxymethane.
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The rate constant of a first order reaction increases from 2 × 10−2 to 4 × 10−2 when the temperature changes from 300 K to 310 K. Calculate the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
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Why do actinoids show a wide range of oxidation states?
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Write on similarity between the chemistry of lanthanoids and actinoids.
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Which of the following is a natural polymer ? Buna-S, Proteins, PVC
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With reference to structural variability and chemical reactivity, write the differences between lanthanoids and actinoids
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What do you understand by the term glycosidic linkage?
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Answer the following question.
Write the products obtained after the hydrolysis of lactose.
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What is the two dimensional coordination number of a molecule in square close packed layer?
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A compound forms hexagonal close-packed structure. What is the total number of voids in 0.5 mol of it? How many of these are tetrahedral voids?
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A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3rdof tetrahedral voids. What is the formula of the compound?
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How many lattice points are there in one unit cell of the following lattice?
Face-centred cubic
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A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?
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Ferric oxide crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.
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