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Match the ions given in Column I with their nature given in Column II.
| Column I | Column II |
| (i) \[\ce{CH3 - \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - \overset{⊕}{C}H - CH3}\] | (a) Stable due to resonance |
| (ii) \[\ce{F3 - \overset{⊕}{C}}\] | (b) Destabilised due to inductive effect |
|
(iii) \[\begin{array}{cc} |
(c) Stabilised by hyperconjugation |
| (iv) \[\ce{CH3 - \overset{⊕}{C}H - CH3}\] | (d) A secondary carbocation |
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Arrange the halogens F2, Cl2, Br2, I2, in order of their increasing reactivity with alkanes.
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The addition of HBr to 1-butene gives a mixture of products A, B and C
| (A) | ![]() |
| (B) | ![]() |
| (C) | CH3 – CH2 – CH2 – CH2 – Br |
The mixture consists of:
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Arrange the following hydrogen halides in order of their decreasing reactivity with propene.
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Which of the following alkenes on ozonolysis give a mixture of ketones only?
| (i) | CH3 – CH = CH – CH3 |
| (ii) | \[\begin{array}{cc} \ce{CH3 - C - CH = CH2}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
| (iii) | ![]() |
| (iv) | \[\begin{array}{cc} \phantom{...................}\ce{CH3}\\ \phantom{..............}/\\ \ce{(CH3)2 C = C}\\ \phantom{..............}\backslash\\ \phantom{...................}\ce{CH3} \end{array}\] |
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In the presence of peroxide addition of HBr to propene takes place according to anti Markovnikov’s rule but peroxide effect is not seen in the case of HCl and HI. Explain.
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An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of ‘A’.
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An alkene ‘A’ contains three C-C, eight C-H σ bonds and one C-C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of ‘A’.
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What is the basic difference between the terms electron gain enthalpy and electronegativity?
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How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds?
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Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number (`bar v`) of the yellow light.
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Find energy of each of the photons which correspond to light of frequency 3 × 1015 Hz.
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Find energy of each of the photons which have the wavelength of 0.50 Å.
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What is the number of photons of light with a wavelength of 4000 pm that provide 1 J of energy?
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A photon of wavelength 4 × 10–7 m strikes on the metal surface, the work function of the metal being 2.13 eV. Calculate
- the energy of the photon (eV),
- the kinetic energy of the emission, and
- the velocity of the photoelectron (1 eV = 1.6020 × 10–19 J).
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A 25-watt bulb emits monochromatic yellow light of the wavelength of 0.57μm. Calculate the rate of emission of quanta per second.
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Electrons are emitted with zero velocity from a metal surface when it is exposed to radiation of wavelength 6800 Å. Calculate threshold frequency (v0) and work function (W0) of the metal.
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Following results are observed when sodium metal is irradiated with different wavelengths. Calculate (a) threshold wavelength and, (b) Planck’s constant.
| λ (nm) | 500 | 450 | 400 |
| v × 10-5 (cm s-1) | 2.55 | 4.35 | 5.35 |
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The electron energy in the hydrogen atom is given by En = (–2.18 × 10–18)/n2 J. Calculate the energy required to remove an electron completely from the n = 2 orbit. What is the longest wavelength of light in cm that can be used to cause this transition?
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In astronomical observations, signals observed from the distant stars are generally weak. If the photon detector receives a total of 3.15 × 10–18 J from the radiations of 600 nm, calculate the number of photons received by the detector.
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