Science (English Medium) कक्षा १२ - CBSE Important Questions

An element crystallizes in a f.c.c. lattice with a cell edge of 250 pm. Calculate the density if 300 g of this element contains 2 × 10²⁴ atoms. 

Calculate the freezing point of solution when 1.9 g of MgCl₂ (M = 95 g mol⁻¹) was dissolved in 50 g of water, assuming MgCl₂ undergoes complete ionization.

(K_f for water = 1.86 K kg mol⁻¹)

Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why?

What happens when the external pressure applied becomes more than the osmotic pressure of solution?

When 2.56 g of sulphur was dissolved in 100 g of CS₂, the freezing point lowered by 0.383 K. Calculate the formula of sulphur (S_x).

(K_f for CS₂ = 3.83 K kg mol⁻¹, Atomic mass of sulphur = 32 g mol⁻¹]

Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing

(i) 1.2% sodium chloride solution?

(ii) 0.4% sodium chloride solution?

What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3^rd of tetrahedral voids?

What is meant by positive deviations from Raoult's law? Give an example. What is the sign of ∆_mixH for positive deviation?

3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van't Hoff factor and predict the nature of solute (associated or dissociated).

(Given : Molar mass of benzoic acid = 122 g mol⁻¹, K_f for benzene = 4.9 K kg mol⁻¹)

An element with molar mass 27 g mol⁻¹ forms a cubic unit cell with edge length 4.05 ✕ 10⁻⁸ cm. If its density is 2.7 g cm⁻³, what is the nature of the cubic unit cell?

Define the following term

Schottky defect

An element with density 2.8 g cm^–3 forms a f.c.c. unit cell with edge length 4 x 10^–8 cm. Calculate the molar mass of the element.

(Given : N_A = 6.022 x 10²³ mol ^–1)

Define the following terms : Molarity

Define the following term: 

Molal elevation constant (K_b)

A solution of glucose (molar mass = 180 g mol^–1) in water is labelled as 10% (by mass). What would be the molality and molarity of the solution ? (Density of solution = 1.2 g mL^–1)

Define Molality.

Write any two differences between amorphous solids and crystalline solids

Give reasons : In stoichiometric defects, NaCl exhibits Schottky defect and not Frenkel defect.

Give reasons : Silicon on doping with Phosphorous forms n-type semiconductor.

An element with density 11.2 g cm^–3 forms a f.c.c. lattice with edge length of 4 × 10^–8 cm.
Calculate the atomic mass of the element.
(Given : N_A = 6.022 × 10²³ mol^–1)