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Write the structure of main compounds A and B in the following reaction:
\[\ce{CH3CH2CN->[CH3MgBRH/3O+]A->[LiAIH4]B}\]
Concept: Methods of Preparation of Alcohols
Why phenol undergoes electrophilic substitution more easily than benzene?
Concept: Methods of Preparation of Phenols
Account for the following:
o-nitrophenol is more steam volatile than p-nitrophenol.
Concept: Chemical Reactions of Alcohols and Phenols >> Reactions Involving Cleavage of O-H Bond
Write the reaction involved in the following:
Friedal-Crafts Alkylation of Phenol
Concept: Chemical Properties of Phenol
Give simple chemical test to distinguish between Ethanol and Phenol.
Concept: Preparation of Commercially Important Alcohols
Give reasons for the following:
Sulphur in vapour state shows paramagnetic behaviour.
Concept: Group 16 Elements - The Oxygen Family >> Sulphur - Allotropic Forms
Give reasons for the following:
Ozone is thermodynamically less stable than oxygen.
Concept: Group 16 Elements - The Oxygen Family >> Ozone
Write the name of gas released when Cu is added to
dilute HNO3
Concept: Group 15 Elements - The Nitrogen Family >> Nitric Acid
Write the name of gas released when Cu is added to
conc. HNO3
Concept: Group 15 Elements - The Nitrogen Family >> Nitric Acid
Arrange the following in the increasing order of their property indicated:
Benzoic acid, Phenol, Picric acid, Salicylic acid (pka values).
Concept: Classification of Alcohols and Phenols
Arrange the following in the increasing order of their property indicated:
ethanol, ethanoic acid, benzoic acid (boiling point)
Concept: Chemical Properties of Alcohols and Phenols
Convert the following:
Phenol to N-phenylethanamide.
Concept: Chemical Properties of Phenol
Convert the following:
Propanenitrile to ethanol.
Concept: Preparation of Commercially Important Alcohols
What happens when reactions:
N-ethylethanamine reacts with benzenesulphonyl chloride.
Concept: Methods of Preparation of Phenols
What happens when reactions:
Benzylchloride is treated with ammonia followed by the reaction with Chloromethane.
Concept: Group 15 Elements - The Nitrogen Family >> Ammonia
The major product of acid catalysed dehydration of 1-methylcyclohexanol is ______.
Concept: Methods of Preparation of Alcohols
Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): An ether is more volatile than an alcohol of comparable molecular mass
Reason (R): Ethers are polar in nature.
Select the most appropriate answer from the options given below:
Concept: Physical Properties of Ethers
Name the suitable alcohol and reagent, from which 2-Chloro-2-methyl propane can be prepared.
Concept: Preparation of Ethers
Write the equations for the following reaction:
Tert butyl chloride is treated with sodium ethoxide.
Concept: Preparation of Ethers
Write the equations for the following reaction:
Phenol is treated with chloroform in the presence of NaOH
Concept: Chemical Properties of Phenol
