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प्रश्न
Write the free radical mechanism for the polymerisation of ethene.
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उत्तर
Polymerization of ethene to polythene consists of heating or exposing to light a mixture of ethene with a small amount of benzoyl peroxide as the initiator.
The reaction involved in this process is given below:
Chain terminating step
संबंधित प्रश्न
How are polythene and neoprene prepared?
Write the molecular formula and structural formula of BHA and BHT.
What is the role of t-butyl peroxide in the polymerization of ethene?
Which of the following is a natural polymer ? Buna-S, Proteins, PVC
Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.
Why should the monomers used in addition polymerisation through free radical pathway be very pure?
Match the polymer of column I with correct monomer of column II.
| Column I | Column II |
| (i) High density polythene | (a) Isoprene |
| (ii) Neoprene | (b) Tetrafluoroethene |
| (iii) Natural rubber | (c) Chloroprene |
| (iv) Teflon | (d) Acrylonitrile |
| (v) Acrilan | (e) Ethene |
Match the polymers given in Column I with their chemical names given in Column II.
| Column I | Column II |
| (i) Nylon 6 | (a) Polyvinyl chloride |
| (ii) PVC | (b) Polyacrylonitrile |
| (iii) Acrilan | (c) Polycaprolactum |
| (iv) Natural rubber | (d) Low-density polythene |
| (v) LDP | (e) cis-polyisoprene |
Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.
| Column I | Column II |
| (i) Nylon-6,6 | (a) Free radical polymerisation |
| (ii) PVC | (b) Ziegler-Natta polymerisation or coordination polymerisation |
| (iii) HDP | (c) Anionic polymerisation |
| (d) Condensation polymerisation |
Assertion: Polytetrafluoroethene is used in making non-stick cookwares.
Reason: Fluorine has highest electronegativity.
Low density polythene and high density polythene, both are polymers of ethene but there is marked difference in their properties. Explain.
The Ziegler Natta catalyst are
Which one of the following polymers is prepared by addition polymerisation?
Orlon fibres are made up of ______.
\[\ce{X + C + Cl2 ->[High temperature][of about 1000 K] Y + CO}\];
\[\ce{Y + 2H2O -> Z + 2HCl}\]
Compound Y is found in polymeric chain structure and is an electron-deficient Molecule. Y must be:
Which of the following statements about low density polythene is false?
