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प्रश्न
Why do gases always tend to be less soluble in liquids as the temperature is raised?
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उत्तर
The solubility of a gas in a liquid at a particular temperature is directly proportional to the pressure of the gas in equilibrium with the liquid at that temperature. The dissolution of a gas in a liquid is an exothermic process, that is, it is accompanied by the evolution of heat. Thus,
\[\ce{Gas + Solvent <=> Solution + Heat}\]
Applying Le Chatelier’s principle, the increase of temperature would shift the equilibrium in the backward direction; that is, solubility would decrease. Therefore, gases always tend to be less soluble in liquids as the temperature is raised.
संबंधित प्रश्न
What is the effect of temperature on solubility of a gas in a liquid?
Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of KH (Henry’s constant) and why
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Which law shows relation between pressure and solubility of a gas in solvent?
According to Henry’s law, the amount of gas that will dissolve in blood plasma or any other liquid is determined by which of these factors?
Henry’s law constant of oxygen is 1.4 × 10–3 mol lit–1 atm–1 at 298 K. How much of oxygen is dissolved in 100 ml at 298 K when the partial pressure of oxygen is 0.5 atm?
Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ______.
The value of Henry's constant KH is ______.
What is the significance of Henry’s Law constant KH?
Match the items given in Column I with the type of solutions given in Column II.
| Column I | Column II |
| (i) Soda water | (a) A solution of gas in solid |
| (ii) Sugar solution | (b) A solution of gas in gas |
| (iii) German silver | (c) A solution of solid in liquid |
| (iv) Air | (d) A solution of solid in solid |
| (v) Hydrogen gas in palladium | (e) A solution of gas in liquid |
| (f) A solution of liquid in solid |
The solubility of a gas in water depends on ______
State Henry’s law and explain why are the tanks used by scuba divers filled with air diluted with helium (11.7% helium, 56.2% nitrogen and 32.1% oxygen)?
If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that dissolve in 1 litre of water is ______. (Nearest integer)
(Given: Henry's Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920 bar)
(Assume solubility of O2 in water is too small, nearly negligible)
Solubility of gas in liquid decreases with increase in ______.
Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water?
- phenol
- toluene
- formic acid
- ethylene glycol
- chloroform
- pentanol
Assertion (A): Helium is used to dilute oxygen in diving apparatus.
Reason (R): Helium has high solubility in O.
In the light of the above statements, choose the correct answer from the options given below:
