Advertisements
Advertisements
प्रश्न
What is the rate constant?
What do you understand by rate constant?
What is meant by the rate constant of a reaction?
Advertisements
उत्तर १
When the concentration (active mass) of each reactant is at unity, the rate constant of a chemical reaction equals the rate of the reaction.
∵ Rate of reaction ∝ [Reactant]
If A → product, then
rate (R) = k[A]
If [A] = 1, then rate, R = k,
where k is the rate constant.
उत्तर २
- The rate constant of a reaction is equal to the rate of reaction when the concentration of each of the reactants is unity.
- At a specific temperature, a reaction's rate constant has a fixed value. As the temperature rises, so does its worth. It is independent of the reactant concentrations at the initiation.
APPEARS IN
संबंधित प्रश्न
A first order reaction has a rate constant 1.15 × 10−3 s−1. How long will 5 g of this reactant take to reduce to 3 g?
In a pseudo first order reaction in water, the following results were obtained:
| t/s | 0 | 30 | 60 | 90 |
| [A]/mol L−1 | 0.55 | 0.31 | 0.17 | 0.085 |
Calculate the average rate of reaction between the time interval 30 to 60 seconds.
The time required for 10% completion of a first order reaction at 298 K is equal to that required for its 25% completion at 308 K. If the value of A is 4 × 1010 s−1. Calculate k at 318 K and Ea.
Following data are obtained for reaction :
N2O5 → 2NO2 + 1/2O2
| t/s | 0 | 300 | 600 |
| [N2O5]/mol L–1 | 1.6 × 10-2 | 0.8 × 10–2 | 0.4 × 10–2 |
1) Show that it follows first order reaction.
2) Calculate the half-life.
(Given log 2 = 0.3010, log 4 = 0.6021)
Define order of reaction. How does order of a reaction differ from molecularity for a complex reaction?
Which of the following graphs is correct for a first order reaction?




First order reaction is 50% complete in 1.26 × 1014s. How much time could it take for 100% completion?
Time required to decompose SO2Cl2 to half of its initial concentration is 60 minutes. If the de-composite is a first order reaction, calculated the rate constant of the reaction-
For a first order reaction, the ratio of the time for 75% completion of a reaction to the time for 50% completion is ______. (Integer answer)
The following data were obtained during the decomposition of SO2Cl2 at the constant volume. SO2Cl2 →SO2(g) + Cl2(g)
| Time (s) | Total Pressure (bar) |
| 0 | 0.5 |
| 100 | 0.6 |
Calculate the rate constant of the reaction.
