हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान कक्षा ११

The value of Kc for the reaction 3O2 (g) ↔ 2O3 (g) is 2.0 ×10–50 at 25°C. If the equilibrium concentration of O2 in the air at 25°C is 1.6 ×10–2, what is the concentration of O3?

Advertisements
Advertisements

प्रश्न

The value of Kc for the reaction 3O2 (g) ↔ 2O3 (g) is 2.0 ×10–50 at 25°C. If the equilibrium concentration of O2 in the air at 25°C is 1.6 ×10–2, what is the concentration of O3?

संख्यात्मक
Advertisements

उत्तर

The given reaction is:

\[\ce{3O_{2(g)} ↔ 2O_{3(g)}}\]

Then `"K"_"C" = (["O"_(3("g"))]^2)/["O"_(2("g"))]^3`

It is given that `"K"_"C" = 2.0 xx 10^(-30) and ["O"_(2("g")]] = 1.6 xx 10^(-2)`

Then, we have,

`2.0 xx 10^(-50) = ["O"_(3("g")]]^2/[1.6 xx 10^(-2)]^3`

`=> ["O"_(3("g"))]^2 = 2.0 xx 10^(-50) xx (1.6 xx 10^(-2))^3`

`=> ["O"_(3("g"))]^2 = 8.192 xx 10^(-56)` 

`=>["O"_(3("g"))] = 2.86 xx 10^(-28) "M"`

Hence, the concentration of `"O"_3 " is " 2.86 xx 10^(-28)` M

shaalaa.com
Law of Chemical Equilibrium and Equilibrium Constant
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 6: Equilibrium - EXERCISES [पृष्ठ २३६]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 11
अध्याय 6 Equilibrium
EXERCISES | Q 7.33 | पृष्ठ २३६

संबंधित प्रश्न

What is Kc for the following equilibrium when the equilibrium concentration of each substance is: [SO2] = 0.60 M, [O2] = 0.82 M and [SO3] = 1.90 M?

\[\ce{2SO2(g) + O2(g) ⇌ 2SO3(g)}\]


Write the expression for the equilibrium constant, Kc for each of the following reactions:

\[\ce{2NOCl (g) ⇌ 2NO (g) + Cl2 (g)}\]


Write the expression for the equilibrium constant, Kc for the following reactions:

\[\ce{2Cu(NO3)2 (s) ⇌ 2CuO (s) + 4NO2 (g) + O2 (g)}\]


Write the expression for the equilibrium constant, Kc for the following reactions:

\[\ce{CH3COOC2H5(aq) + H2O(l) ⇌CH3COOH (aq) + C2H5OH (aq)}\]


Nitric oxide reacts with Br2 and gives nitrosyl bromide as per reaction given below:

\[\ce{2NO(g) + Br2 (g) ⇌ 2NOBr (g)}\]

When 0.087 mol of NO and 0.0437 mol of Br2 are mixed in a closed container at the constant temperature, 0.0518 mol of NOBr is obtained at equilibrium. Calculate the equilibrium amount of NO and Br2.


One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium, 40% of water (by mass) reacts with CO according to the equation, 

\[\ce{H2O (g) + CO (g) ⇌ H2 (g) + CO2 (g)}\] 

Calculate the equilibrium constant for the reaction.


What is the equilibrium concentration of each of the substances in the equilibrium when the initial concentration of ICl was 0.78 M?

\[\ce{2 ICl(g) ⇌  I2(g) + Cl2(g)}\]; KC = 0.14


Kp = 0.04 atm at 899 K for the equilibrium shown below. What is the equilibrium concentration of C2H6 when it is placed in a flask at 4.0 atm pressure and allowed to come to equilibrium?

\[\ce{C2H6 (g) ⇌ C2H4 (g) + H2 (g)}\]


The reaction, \[\ce{CO(g) + 3H2(g) ↔ CH4(g) + H2O(g)}\] is at equilibrium at 1300 K in a 1L flask. It also contains 0.30 mol of CO, 0.10 mol of H2 and 0.02 mol of H2O and an unknown amount of CH4 in the flask. Determine the concentration of CH4 in the mixture. The equilibrium constant, Kc for the reaction at the given temperature is 3.90.


Match standard free energy of the reaction with the corresponding equilibrium constant.

Column I Column II
(i) ∆GΘ > 0 (a) K > 1
(ii) ∆GΘ > 0  (b) K = 1
(iii) ∆GΘ = 0 (c) K = 0
  (d) K < 1

For the reaction,

\[\ce{N2 + O2(g) ⇌ 2NO(g)}\]

the equilibrium constant is K1. The equilibrium constant is K2 for the reaction

\[\ce{2NO(g) + O2(g) ⇌ 2NO2(g)}\]

What is "K" for the reaction:

\[\ce{NO2(g) ⇌ 1/2 N2(g) + O2(g)}\]?


At 1990 K and 1 atm pressure, there are equal numbers of Cl2 molecules and Cl atoms in the reaction mixture. The value of Kp for the reaction Cl2(g) ⇌ 2Cl(g) under the above conditions is x × 10−1. The value of x is ______. (Rounded-off to the nearest integer)


For the reaction \[\ce{A(g) <=> B(g)}\] at 495 K, ΔG° = −9.478 kJ mol−1

If we start the reaction in a closed container at 495 K with 22 millimoles of A, the amount of B in the equilibrium mixture is ______ millimoles. (Round off to the Nearest Integer).

[R = 8.314 J mol−1 K−1; ln 10 = 2.303]


An equilibrium system for the reaction between hydrogen and iodine to give hydrogen iodide at 765 K in a 5 litre volume contains 0.4 mole of hydrogen, 0.4 mole of iodine and 2.4 moles of hydrogen iodide.

\[\ce{H2 + I2 <=> 2HI}\]

The equilibrium constant for the reaction is:


Sulphide ion in alkaline solution reacts with solid sulphur to form polysulphide ions having formula, \[\ce{S^{2-}2}\], \[\ce{S^{2-}3}\], \[\ce{S^{2-}4}\], etc. if K1 = 12 for \[\ce{S + S^{2-} <=> S^{2-}2}\] and K2 = 132 for \[\ce{2S + S^{2-} <=> S^{2-}3}\], K3 = ______ for \[\ce{S + S^{2-}2 <=> S^{2-}3}\].


The equilibrium constant for the reaction is ______ × 1026.

\[\ce{Fe + CuSO4 <=> FeSO4 + Cu}\] at 25°C.

Given `"E"_("Fe"//"Fe"^(2+))^0` = 0.44 V

`"E"_("Cu"//"Cu"^(2+))^0` = - 0.337 V


The decomposition of N2O4 to NO2 was carried out in chloroform at 280°C. At equilibrium, 0.2 mol of N2O4 and 2 × 10−3 mol of NO2 were present in 2 ℓ of the solution. The equilibrium constant for the reaction \[\ce{N2O4 <=> 2NO2}\] is ______.


In which one of the following equilibria, KP ≠ Kc?


In which of the following equilibria, Kp and Kc are not equal?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×