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प्रश्न
The Q value of a nuclear reaction \[\ce{A + b → C + d}\] is defined by
Q = [ mA+ mb− mC− md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
\[\ce{^1_1H + ^3_1H -> ^2_1H + ^2_1H}\]
Atomic masses are given to be
`"m"(""_1^2"H")` = 2.014102 u
`"m"(""_1^3"H")` = 3.016049 u
`"m"(""_6^12"C")` = 12.000000 u
`"m"(""_10^20"Ne")` = 19.992439 u
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उत्तर
The given nuclear reaction is:
\[\ce{^1_1H + ^3_1H -> ^2_1H + ^2_1H}\]
It is given that:
Atomic mass `m(""_1^1"H")` = 1.007825 u
Atomic mass `m(""_1^3"H")` = 3.016049 u
Atomic mass `m(""_1^2"H") = 2.014102 u`
According to the question, the Q-value of the reaction can be written as:
Q = `["m"(""_1^1"H") + "m"(""_1^3"H") - 2"m"(""_1^2"H")]"c"^2`
Q = (- 0.00433 c2)u
But 1 u = 931.5 MeV/c2
`= [1.007825 + 3.016049 - 2 xx 2.014102]c^2`
`"Q" = - 0.00433 xx 931.5 = - 4.0334` MeV
The negative Q-value of the reaction shows that the reaction is endothermic.
संबंधित प्रश्न
Obtain the relation between the decay constant and half life of a radioactive sample.
(a) Derive the relation between the decay constant and half life of a radioactive substance.
(b) A radioactive element reduces to 25% of its initial mass in 1000 years. Find its half life.
In a given sample, two radioisotopes, A and B, are initially present in the ration of 1 : 4. The half lives of A and B are respectively 100 years and 50 years. Find the time after which the amounts of A and B become equal.
28Th emits an alpha particle to reduce to 224Ra. Calculate the kinetic energy of the alpha particle emitted in the following decay:
`""^228"Th" → ""^224"Ra"^(∗) + alpha`
`""^224"Ra"^(∗) → ""^224"Ra" + γ (217 "keV")`.
Atomic mass of 228Th is 228.028726 u, that of 224Ra is 224.020196 u and that of `""_2^4H` is 4.00260 u.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
Calculate the maximum kinetic energy of the beta particle emitted in the following decay scheme:
12N → 12C* + e+ + v
12C* → 12C + γ (4.43MeV).
The atomic mass of 12N is 12.018613 u.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
The decay constant of 238U is 4.9 × 10−18 S−1. (a) What is the average-life of 238U? (b) What is the half-life of 238U? (c) By what factor does the activity of a 238U sample decrease in 9 × 109 years?
What is the amount of \[\ce{_27^60Co}\] necessary to provide a radioactive source of strength 10.0 mCi, its half-life being 5.3 years?
A source contains two species of phosphorous nuclei, \[\ce{_15^32P}\] (T1/2 = 14.3 d) and \[\ce{_15^33P}\] (T1/2 = 25.3 d). At time t = 0, 90% of the decays are from \[\ce{_15^32P}\]. How much time has to elapse for only 15% of the decays to be from \[\ce{_15^32P}\]?
After 1 hour, `(1/8)^"th"` of the initial mass of a certain radioactive isotope remains undecayed. The half-life of the isotopes is ______.
Two radioactive materials Y1 and Y2 have decay constants '5`lambda`' and `lambda` respectively. Initially they have same number of nuclei. After time 't', the ratio of number of nuclei of Y1 to that of Y2 is `1/"e"`, then 't' is equal to ______.
What percentage of radioactive substance is left after five half-lives?
Two electrons are ejected in opposite directions from radioactive atoms in a sample of radioactive material. Let c denote the speed of light. Each electron has a speed of 0.67 c as measured by an observer in the laboratory. Their relative velocity is given by ______.
If 10% of a radioactive material decay in 5 days, then the amount of original material left after 20 days is approximately :
Suppose we consider a large number of containers each containing initially 10000 atoms of a radioactive material with a half life of 1 year. After 1 year ______.
Samples of two radioactive nuclides A and B are taken. λA and λB are the disintegration constants of A and B respectively. In which of the following cases, the two samples can simultaneously have the same decay rate at any time?
- Initial rate of decay of A is twice the initial rate of decay of B and λA = λB.
- Initial rate of decay of A is twice the initial rate of decay of B and λA > λB.
- Initial rate of decay of B is twice the initial rate of decay of A and λA > λB.
- Initial rate of decay of B is the same as the rate of decay of A at t = 2h and λB < λA.
The variation of decay rate of two radioactive samples A and B with time is shown in figure.

Which of the following statements are true?
- Decay constant of A is greater than that of B, hence A always decays faster than B.
- Decay constant of B is greater than that of A but its decay rate is always smaller than that of A.
- Decay constant of A is greater than that of B but it does not always decay faster than B.
- Decay constant of B is smaller than that of A but still its decay rate becomes equal to that of A at a later instant.
Which sample, A or B shown in figure has shorter mean-life?

Consider a radioactive nucleus A which decays to a stable nucleus C through the following sequence:
A→B→C
Here B is an intermediate nuclei which is also radioactive. Considering that there are N0 atoms of A initially, plot the graph showing the variation of number of atoms of A and B versus time.
The activity R of an unknown radioactive nuclide is measured at hourly intervals. The results found are tabulated as follows:
| t (h) | 0 | 1 | 2 | 3 | 4 |
| R (MBq) | 100 | 35.36 | 12.51 | 4.42 | 1.56 |
- Plot the graph of R versus t and calculate the half-life from the graph.
- Plot the graph of ln `(R/R_0)` versus t and obtain the value of half-life from the graph.
