Advertisements
Advertisements
प्रश्न
The initial pressure and volume of a given mass of a gas (Cp/Cv = γ) are p0 and V0. The gas can exchange heat with the surrounding. (a) It is slowly compressed to a volume V0/2 and then suddenly compressed to V0/4. Find the final pressure. (b) If the gas is suddenly compressed from the volume V0 to V0/2 and then slowly compressed to V0/4, what will be the final pressure?
Advertisements
उत्तर
Given:
For the gas, `("C"_"p")/"C"_"v" = gamma`
Initial pressure of the gas = P0
Initial volume of the gas = V0
(a)
(i) As the gas is slowly compressed, its temperature will remain constant.
For isothermal compression,
P1V1 = P2V2
So, P0V0 =P2 `"V"_0/2 =>"P"_2 = 2"P"_0`
(ii) Sudden compression means that the gas could not get sufficient time to exchange heat with its surroundings. So, it is an adiabatiac compression.
So, for adiabatic compression,
P1V1γ = P2V2γ Or
`2"P"_0 ("V"_0/2)^gamma = "P"_2 ("V"_0/4)^ gamma`
`=> "P"_2 = "V"_0^gamma/2^ gamma xx 2"P"_0 xx 4^gamma/"V"_0^gamma`
= 2γ × 2P0 = P02γ+1
(b)
(i) Adiabatic compression:
P1V1γ = P2V2γ
`"P"_0"V"_0 ^ gamma = "P'"("V"_0/2)^ gamma`
⇒ P' = P02γ
(ii) Isothermal compression:
P1V1 = P2V2
`2 ^ gamma "P"_0 xx "V"_0/2 = "P''" ("V_0/2)`
P" = P02γ × 2
⇒ P" = P02γ+1
APPEARS IN
संबंधित प्रश्न
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3 s–1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3 s–1. Identify the gas
[Hint: Use Graham’s law of diffusion: R1/R2 = (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Figure shows graphs of pressure vs density for an ideal gas at two temperatures T1 and T2.
The pressure of a gas kept in an isothermal container is 200 kPa. If half the gas is removed from it, the pressure will be
2 g of hydrogen is sealed in a vessel of volume 0.02 m3 and is maintained at 300 K. Calculate the pressure in the vessel.
Use R=8.3J K-1 mol-1
Air is pumped into an automobile tyre's tube up to a pressure of 200 kPa in the morning when the air temperature is 20°C. During the day the temperature rises to 40°C and the tube expands by 2%. Calculate the pressure of the air in the tube at this temperature.
A vessel contains 1.60 g of oxygen and 2.80 g of nitrogen. The temperature is maintained at 300 K and the volume of the vessel is 0.166 m3. Find the pressure of the mixture.
Use R = 8.3 J K-1 mol-1
A container of volume 50 cc contains air (mean molecular weight = 28.8 g) and is open to atmosphere where the pressure is 100 kPa. The container is kept in a bath containing melting ice (0°C). (a) Find the mass of the air in the container when thermal equilibrium is reached. (b) The container is now placed in another bath containing boiling water (100°C). Find the mass of air in the container. (c) The container is now closed and placed in the melting-ice bath. Find the pressure of the air when thermal equilibrium is reached.
Use R = 8.3 J K-1 mol-1
In an adiabatic process on a gas with γ = 1.4, the pressure is increased by 0.5%. The volume decreases by about
An ideal gas is kept in a long cylindrical vessel fitted with a frictionless piston of cross-sectional area 10 cm2 and weight 1 kg. The length of the gas column in the vessel is 20 cm. The atmospheric pressure is 100 kPa. The vessel is now taken into a spaceship revolving round the earth as a satellite. The air pressure in the spaceship is maintained at 100 kPa. Find the length of the gas column in the cylinder.
Use R = 8.3 J K-1 mol-1
A gas is enclosed in a cylindrical can fitted with a piston. The walls of the can and the piston are adiabatic. The initial pressure, volume and temperature of the gas are 100 kPa, 400 cm3 and 300 K, respectively. The ratio of the specific heat capacities of the gas, Cp / Cv = 1.5. Find the pressure and the temperature of the gas if it is (a) suddenly compressed (b) slowly compressed to 100 cm3.
Two glass bulbs of equal volume are connected by a narrow tube and are filled with a gas at 0°C at a pressure of 76 cm of mercury. One of the bulbs is then placed in melting ice and the other is placed in a water bath maintained at 62°C. What is the new value of the pressure inside the bulbs? The volume of the connecting tube is negligible.
Three samples A, B and C of the same gas (γ = 1.5) have equal volumes and temperatures. The volume of each sample is doubled, the process being isothermal for A, adiabatic for B and isobaric for C. If the final pressures are equal for the three samples, find the ratio of the initial pressures.
The human body has an average temperature of 98°F. Assume that the vapour pressure of the blood in the veins behaves like that of pure water. Find the minimum atmospheric pressure which is necessary to prevent the blood from boiling. Use figure for the vapour pressures.
A barometer correctly reads the atmospheric pressure as 76 cm of mercury. Water droplets are slowly introduced into the barometer tube by a dropper. The height of the mercury column first decreases and then becomes constant. If the saturation vapour pressure at the atmospheric temperature is 0.80 cm of mercury, find the height of the mercury column when it reaches its minimum value.
A faulty barometer contains certain amount of air and saturated water vapour. It reads 74.0 cm when the atmospheric pressure is 76.0 cm of mercury and reads 72.10 cm when the atmospheric pressure is 74.0 cm of mercury. Saturation vapour pressure at the air temperature = 1.0 cm of mercury. Find the length of the barometer tube above the mercury level in the reservoir.
A bucket full of water is placed in a room at 15°C with initial relative humidity 40%. The volume of the room is 50 m3. (a) How much water will evaporate? (b) If the room temperature is increased by 5°C, how much more water will evaporate? The saturation vapour pressure of water at 15°C and 20°C are 1.6 kPa and 2.4 kPa respectively.
Use R = 8.3 J K-1 mol-1
Air separated from the atmosphere by a column of mercury of length h = 15 cm is present in a narrow cylindrical two-soldered at one end. When the tube is placed horizontally the air occupies a volume V1 = 240 mm3. When it is set vertically with its open end upwards the volume of the air is V2 = 200 mm3. The atmospheric pressure during the experiment is 7n cm of Hg where n is a single digit number. n will be ______.
