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How will you distinguish NH4OH solution from NaOH solution?

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प्रश्न

How will you distinguish NH4OH solution from NaOH solution?

How will you differentiate between ammonium hydroxide and sodium hydroxide solution?

अंतर स्पष्ट करें
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उत्तर

NH4OH and NaOH can be distinguished by using calcium salts.

For example, when NaOH is added to Ca(NO3)2, Ca(OH)2 is obtained as a white precipitate that is sparingly soluble in excess of NaOH.

\[\ce{Ca(NO3)2 + 2NaOH → Ca(OH)2 + 2NaNO3}\]

When NH4OH is added to calcium salts, no precipitation of Ca(OH)2 occurs, even with an excess of NH4OH. This is because the concentration of OH−ions from the ionization of NH4OH is so low that it cannot precipitate the calcium hydroxide.

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Action of Ammonium Hydroxide on Certain Salt Solutions
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अध्याय 4: Analytical Chemistry - lntext Questions [पृष्ठ ७०]

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संबंधित प्रश्न

Name the metal hydroxides which are soluble in ammonium hydroxide solution.


Choose the correct answer from the options given below :
A chloride which forms a precipitate that is soluble in excess of ammonium hydroxide is :


State what do you observe when ammonium hydroxide to Iron (III) sulphate solution.


Write the observation for the following:
NaOH is added drop-wise till in excess to a solution of zinc sulphate.


What would you observe in the following case:

Ammonium hydroxide is first added in a small quantity and then in excess to a solution of copper sulphate.


The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present

Chemical Test

Observation Conclusion
To Solution X, ammonium hydroxide is added in minium quantity first and then in excess A dirty white precipitate is formed which dissolves in excess to form a clear solution (i)
To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution (ii)
To solution W, A small quantity of sodium hydroxide solution is added and then in excess A white precipitate is formed which remains insoluble (iii)
To a salt Z, calcium hydroxide solution is added and then heated A pungent smelling gas turning moist red litmus paper blue is obtained (iv)

Write balanced equation copper sulphate solution with ammonium hydroxide solution.


Write balanced equation:

Copper sulphate solution with ammonium hydroxide solution.


______ is a white precipitate that is soluble in excess of Ammonium hydroxide solution.


Write a balanced equation:

Copper sulphate solution with ammonium hydroxide solution.


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