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प्रश्न
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Account for the following:
Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).
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उत्तर
Primary amines exhibit intermolecular hydrogen bonding, necessitating greater energy to disrupt the attraction. In tertiary amines, intermolecular hydrogen bonding is absent.
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संबंधित प्रश्न
Identify the weakest base amongst the following :
(a) p- methoxyaniline
(b) o-toluidine
(c) benzene - 1, 4 - diamine
(d) 4 - aminobenzoic acid
Arrange the following in increasing order of their basic strength :
- Write structures of different isomeric amines corresponding to the molecular formula C4H11N.
- Write the IUPAC names of all the isomers.
- What type of isomerism is exhibited by different pairs of amines?
How will you convert Benzene into N, N-dimethylaniline?
Answer in one sentence.
Arrange the following amines in increasing order of boiling points.
n-propylamine, ethylmethyl amine, trimethylamine.
Arrange the following compounds in increasing order of their boiling points.
Ethyl alcohol, Ethyl amine, Ethanoic acid, Ethane
Which of the following should be most volatile?
A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
Which of the following have less melting point than amine?
Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
