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प्रश्न
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Account for the following:
Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).
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उत्तर
Primary amines exhibit intermolecular hydrogen bonding, necessitating greater energy to disrupt the attraction. In tertiary amines, intermolecular hydrogen bonding is absent.
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संबंधित प्रश्न
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
Complete the following acid-base reaction and name the product:
\[\ce{CH3CH2CH2NH2 + HCl ->}\]
Complete the following reaction:
\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]
Give reasons CH3NH2 is more basic than C6H5NH2.
Arrange the following compounds in increasing order of their boiling points.
Ethyl alcohol, Ethyl amine, Ethanoic acid, Ethane
Among the following isomeric amines, an amine having highest boiling point is:
Which of the following compound gives a secondary amine oh reduction?
Arrange the following in increasing order of their boiling point:
C2H5OH, C2H5NH2, (C2H5)3N
Write short note on the following:
Ammonolysis
