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प्रश्न
Explain the Structure of Diborane.
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उत्तर
B2H6 is an electron-deficient compound. B2H6 has only 12 electrons – 6 e– from 6 H atoms and 3 e– each from 2 B atoms. Thus, after combining with 3 H atoms, none of the boron atoms has any electrons left. X-ray diffraction studies have shown the structure of diborane as:
2 boron and 4 terminal hydrogen atoms (Ht) lie in one plane, while the other two bridging hydrogen atoms (Hb) lie in a plane perpendicular to the plane of boron atoms. Again, of the two bridging hydrogen atoms, one H atom lies above the plane and the other lies below the plane. The terminal bonds are regular two-centre two-electron (2c – 2e–) bonds, while the two bridging (B–H–B) bonds are three-centre two-electron (3c – 2e–) bonds.
संबंधित प्रश्न
A certain salt X, gives the following results.
- Its aqueous solution is alkaline to litmus.
- It swells up to a glassy material Y on strong heating.
- When conc. H2SO4 is added to a hot solution of X, white crystal of an acid Z separates out.
Write equations for all the above reactions and identify X, Y and Z.
Write a balanced equation for B2H6 + H2O → ?
Write a balanced equation for \[\ce{H3BO3 ->[\Delta]}\]?
Boric acid is polymeric due to ______.
An aqueous solution of borax is _______.
Draw the structures of BCl3.NH3 and AlCl3 (dimer).
Explain the nature of boric acid as a Lewis acid in water.
Draw the structure of boric acid showing hydrogen bonding. Which species is present in water? What is the hybridisation of boron in this species?
When aqueous solution of borax is acidified with hydrochloric acid, a white crystalline solid is formed which is soapy to touch. Is this solid acidic or basic in nature? Explain.
A compound (A) of boron reacts with NMe3 to give an adduct (B) which on hydrolysis gives a compound (C) and hydrogen gas. Compound (C) is an acid. Identify the compounds A, B and C. Give the reactions involved.
Aqueous solution of which of the following boron compounds will be strongly basic in nature?
Boric acid heated to red hot gives ______.
On the addition of mineral acid to an aqueous solution of borax, the compound formed is ______.
When aqueous solution of AICl3 is concentrated, it furnishes crystals of ______.
Boric acid (H3BO3) is ______.
Borazine, also known as inorganic benzene, can be prepared by the reaction of 3-equivalents of “X” with 6-equivalents of “Y”. “X” and “Y”, respectively are ______.
