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प्रश्न
Describe what happens to the iron object and the copper rod.
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उत्तर
The copper anode continuously dissolves as ions in solution and is replaced periodically. The electrolyte dissociates into Cu2+ ions, which migrate towards the iron object taken as the cathode and are deposited as neutral copper atoms on the cathode.
Electrolyte: Aqueous solution of nickel sulphate
Dissociation: \[\ce{CuSO4 ⇌ Cu^2^+ + SO^2^-4}\]
\[\ce{H2O ⇌ H^+ + OH^-}\]
Electrodes:
- Cathode: Article to be electroplated
- Anode: Block of pure copper
Electrode reactions:
- Reaction at cathode: \[\ce{Cu^{2+} + 2e^- -> Cu}\] (deposited)
- Reaction at anode: \[\ce{Cu - 2e^- -> Cu^{2+}}\]
संबंधित प्रश्न
Name the metallic ions that should be present in the electrolyte when an article made of copper is to be electroplated with silver.
Give reasons why In the electroplating of an article with silver, the electrolyte sodium argentocyanide solution is preferred over silver nitrate solution.
State one relevant observation for the following:
At the anode when aqueous copper sulphate solution is electrolysed using copper electrodes.
Choose the correct answer from the options given below:
The electrolyte used for electroplating an article with silver is
A. Silver nitrate solution
B. Silver cyanide solution
C. Sodium argentocyanide solution
D. Nickel sulfate solution
How would you change Cu2+ ion to Cu?
An electrolytic cell is set up using two platinum electrodes and an aqueous solution of copper (II) sulphate,
(a)draw a labelled diagram of the electrolytic cell,
(b)Name the ions present in the cell,
(c)Name the ions migrating towards the anode,
(d)Name the ions migrating towards the cathode,
(e)Name the ions which will not be discharged at electrodes during electrolysis,
(f)Write the reaction at the cathode,
(g)Write the reaction at the anode,
(h)Name the spectator ion in the solution.
State the electrode reaction at the anode during electrolysis of:
Aqueous copper sulphate solution.
Give reason for the following:
The blue colour of aqueous copper sulphate fades when it is electrolysed using platinum electrodes.
Mr Ramu wants electrolyte his key chain with nickel to prevent rusting. For this electroplating
(i) Name the electrolyte
(ii) Name the cathode
(iii) Name the anode
(iv) Give the reaction at the cathode
(v) Give the reaction at the anode
Draw a labelled diagram to show how iron is electroplated with copper.
