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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Zirconium can be purificed by Van Arkel method. Reason: ZrI4 is volatile and decomposes at 1800 K.

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प्रश्न

Assertion: Zirconium can be purificed by Van Arkel method.

Reason: ZrI4 is volatile and decomposes at 1800 K.

विकल्प

  • Both assertion and reason are true and reason is the correct explanation of assertion.

  • Both assertion and reason are true but reason is not the correct explanation of assertion.

  • Assertion is true but reason is false.

  • Assertion is false but reason is true.

  • Assertion and reason both are wrong.

MCQ
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उत्तर

Both assertion and reason are true and reason is the correct explanation of assertion.

Explanation:

van Arkel method is very useful for removing all the oxygen and nitrogen present in the form of impurity in certain metals like Zr and Ti.The crude metal is heated in an evacuated vessel with iodine. The metal iodide being more covalent, volatilises and then decomposes at 1800 K to given pure Zr.

\[\ce{Zr + 2I2 -> ZrI4}\]

\[\ce{ZrI4 ->[1800K] Zr + 2I2}\]

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अध्याय 6: General Principle and Processes of Isolation of Elements - Multiple Choice Questions (Type - I) [पृष्ठ ८५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 6 General Principle and Processes of Isolation of Elements
Multiple Choice Questions (Type - I) | Q 51 | पृष्ठ ८५

संबंधित प्रश्न

Name the method used for the refining of zirconium.


Explain the principle of the method of electrolytic refining of metals. Give one example.


Explain column chromatography.


What criterion is followed for the selection of the stationary phase in chromatography?


Out of PbS and PbCO3 (ores of lead), which one is concentrated by froth floatation process preferably?


Write the chemical equations involved in van Arkel method for refining zirconium metal.


Outline the principles behind the refining of metals by the following methods:

Chromatographic method


Write down the reaction taking place in blast furnace related to the metallurgy of iron in the temperature rnge 500 K – 800 K. What is the role of limestone in the metallurgy of iron? 


What happens when Copper matte is charged into silica lined converter and hot air blast is blown? 


In the extraction of chlorine from brine:

(i) ∆GΘ for the overall reaction is negative.

(ii) ∆GΘ for the overall reaction is positive.

(iii) EΘ for overall reaction has negative value.

(iv) EΘ for overall reaction has positive value.


Why is an external emf of more than 2.2 V required for the extraction of \[\ce{Cl2}\] from brine?


Write two basic requirements for refining of a metal by Mond process and by Van Arkel Method.


Assertion: Nickel can be purified by Mond process.

Reason: \[\ce{Ni(CO)4}\] is a volatile compound which decomposes at 460 K to give pure Ni.


Electrolytic reduction method is used for the extraction of ______.


Describe a method for refining nickel.


Describe a method for refining nickel.


Describe a method for refining nickel.


Describe a method for refining nickel.


Describe a method for refining nickel.


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