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प्रश्न
A compound forms hexagonal close-packed structure. What is the total number of voids in 0.5 mol of it? How many of these are tetrahedral voids?
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उत्तर
Number of close-packed particles = 0.5 × 6.022 × 1023 = 3.011 × 1023
Therefore, number of octahedral voids = 3.011 × 1023
And, number of tetrahedral voids = 2 × 3.011 × 1023 = 6.022 ×1023
Therefore, total number of voids = 3.011 × 1023 + 6.022 × 1023 = 9.033 × 1023
संबंधित प्रश्न
What is the two dimensional coordination number of a molecule in square close packed layer?
How many lattice points are there in one unit cell of the following lattice?
Face-centred cubic
Hexagonal close packed arrangement of ions is described as ____________.
What is the coordination number in a square close packed structure in two dimensions?
In NaCl structure ____________.
Match the type of packing given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Square close packing in two dimensions |
(a) Triangular voids |
| (ii) Hexagonal close packing in two dimensions |
(b) Pattern of spheres is repeated in every fourth layer |
| (iii) Hexagonal close packing in three dimensions |
(c) Coordination number 4 |
| (iv) Cubic close packing in three dimensions |
(d) Pattern of sphere is repeated in alternate layers |
Total no. of voids in 0.5 mole of a compound forming hexagonal closed packed structure are:-
The packing efficiency of the two dimensional square unit cell shown below is:
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The number of tetrahedral and octahedral voids in a CCP array of 100 atoms are respectively:
The right option for the number of tetrahedral and octahedral voids in the hexagonal primitive unit cell is ______.
The right options for the number of tetrahedral and octahedral voids in the hexagonal primitive unit cells is ______.
Element 'B' forms ccp structures and A occupies half of the octahedral voids, while oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is ______.
Ionic radii of cation A+ and anion B- are 102 and 181 pm respectively. These ions are allowed to crystallize into an ionic solid. This crystal has cubic close packing for B-. A+ is present in all octahedral voids. The edge length of the unit cell of the crystal AB is ______ pm. (Nearest integer)
The density of a pure substance 'X' whose atoms pack in cubic close pack arrangement is 1 g/cc. If all tetrahedral voids are occupied by 'Y' atoms. The value of '3a' is ______ g/cc, if the density of resulting solid is 'a' g/cc.
[Given: Atomic mass (X) = 30 g/mol, (Y) = 20 g/mol]
