Advertisements
Advertisements
प्रश्न
A compound forms hexagonal close-packed structure. What is the total number of voids in 0.5 mol of it? How many of these are tetrahedral voids?
Advertisements
उत्तर
Number of close-packed particles = 0.5 × 6.022 × 1023 = 3.011 × 1023
Therefore, number of octahedral voids = 3.011 × 1023
And, number of tetrahedral voids = 2 × 3.011 × 1023 = 6.022 ×1023
Therefore, total number of voids = 3.011 × 1023 + 6.022 × 1023 = 9.033 × 1023
संबंधित प्रश्न
A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?
Hexagonal close packed arrangement of ions is described as ____________.
The arrangement ABC ABC.... is referred to as ____________.
What is the coordination number in a square close packed structure in two dimensions?
Which of the following statement is not true about the hexagonal close packing?
Match the type of packing given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Square close packing in two dimensions |
(a) Triangular voids |
| (ii) Hexagonal close packing in two dimensions |
(b) Pattern of spheres is repeated in every fourth layer |
| (iii) Hexagonal close packing in three dimensions |
(c) Coordination number 4 |
| (iv) Cubic close packing in three dimensions |
(d) Pattern of sphere is repeated in alternate layers |
With the help of a labelled diagram show that there are four octahedral voids per unit cell in a cubic close packed structure.
The crystal system of a compound with unit cell dimensions a = 0.387, b = 0.387 and c = 0.504 nm and α = β = 90° and ϒ = 120° is
Total no. of voids in 0.5 mole of a compound forming hexagonal closed packed structure are:-
The packing efficiency of the two dimensional square unit cell shown below is:
A compound forms hexagonal close-packed structure. What is the total number of voids in 0.5 mol of it? How many of these are tetrahedral voids?
Which of the following is frenkal effect.
The number of tetrahedral and octahedral voids in a CCP array of 100 atoms are respectively:
The right options for the number of tetrahedral and octahedral voids in the hexagonal primitive unit cells is ______.
Element 'B' forms ccp structures and A occupies half of the octahedral voids, while oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is ______.
Ionic radii of cation A+ and anion B- are 102 and 181 pm respectively. These ions are allowed to crystallize into an ionic solid. This crystal has cubic close packing for B-. A+ is present in all octahedral voids. The edge length of the unit cell of the crystal AB is ______ pm. (Nearest integer)
What fraction of one edge centred octahedral void lies in one unit cell of FCC?
