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Karnataka Board PUCPUC Science 2nd PUC Class 12

Concepts of Aldehydes, Ketones, and Carboxylic Acids - Chemical Reactions of Aldehydes and Ketones - Reduction

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Estimated time: 2 minutes
CBSE: Class 12

Key Points: Chemical Reactions of Aldehydes and Ketones - Reduction

\[\text{R}-\text{CHO} + 2[\text{H}] \xrightarrow[\text{or BH}_3]{\text{LiAlH}_4} \text{RCH}_2\text{OH}\]

\[\begin{array}{r@{\;}c@{\;}l r@{\;}c@{\;}l} \ce{R} & & & \ce{R} & & \\ & \backslash & & & \backslash & \\ & & \ce{C=O + H2 ->[Ni or Pt]} & & & \ce{CH2OH} \\ & / & & & / & \\ \ce{R} & & & \ce{R} & & \end{array}\]

Clemmensen reduction:

\begin{array}{r@{\;}c@{\;}l c r@{\;}c@{\;}l} & & & & & & \\ & \backslash & & & & \backslash & \\ & & \ce{C=O} & \xrightarrow[\text{HCl}]{\text{Zn-Hg}} & & & \ce{CH2 + H2O} \\ & / & & & & / & \\ & & & & & & \end{array}

Wolff-Kishner reduction:

\begin{array}{r@{\;}c@{\;}l c r@{\;}c@{\;}l c r@{\;}c@{\;}l} & & & & & & & & & & \\ & \backslash & & & & \backslash & & & & \backslash & \\ & & \ce{C=O} & \xrightarrow[-\ce{H2O}]{\ce{NH2NH2}} & & & \ce{C=NNH2} & \xrightarrow{\text{KOH ethylene Glycol, }\Delta} & & & \ce{CH2 + N2} \\ & / & & & & / & & & & / & \\ & & & & & & & & & & \end{array}

Shaalaa.com | Aldehydes Ketones part 16 (Reduction)

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Aldehydes Ketones part 16 (Reduction) [00:19:06]
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