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Draw a neat and well labelled diagram of primary reference electrode.
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How is 1-nitropropane prepared from suitable oxime?
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How are 2 - nitropropane prepared from suitable oxime?
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Write the reaction for the preparation of Nylon-6.
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Write the reactions involved in dehydration of 1°, 2° and 3° alcohols.
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How are 1 - nitropropane, 2-nitropropane and 2-methyl 2- nitropropane are distinguished from each other using nitrous acid?
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Phenelzine is used as an
(a) analgesic
(b) antiseptic
(c) antipyretic
(d) antidepressant
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The integrated rate equation for first order reaction is A → products
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Derive the relation between half life and rate constant for a first order reaction
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Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer
|
Element |
Al(s) |
Cu(s) |
Cl(aq) |
Ni(s) |
|
Eo |
-1.66V |
0.34V |
1.36V |
-0.26V |
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1.0 x10-3Kg of urea when dissolved in 0.0985 Kg of a solvent, decreases freezing point of the solvent by 0.211 k. 1.6x10 Kg of another non-electrolyte solute when dissolved in 0.086 Kg of the same solvent depresses the freezing point by 0.34 K. Calculate the molar mass of the another solute. (Given molar mass of urea = 60)
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Write one statement of first law of thermodyamics and its mathematical expression.
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Write one statement of first law of thermodyamics and its mathematical expression.
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Calculate Ecell and ΔG for the following at 28°C :
Mg(s) + Sn2+( 0.04M ) → Mg2+( 0.06M ) + Sn(s)
E°cell = 2.23V. Is the reaction spontaneous ?
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Identify the product ‘D’ in the following sequence of reactions:
\[\ce{H3C - CH2 - CH2 - Cl \underset{KOH}{\overset{Alc}{->}} 'B' \overset{HBr}{->} 'C' \underset{Elther}{\overset{Na}{->}}'D'}\]
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Primary and secondary nitroalcanes containing α - H atom show property of -
- chain isomerism
- tautomerism
- optical isomerism
- geometrical isomerism
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Write mechanism of Aldol addition reaction.
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The hybridisation of phosphorus in phosphorus pentachloride is _______.
(A) dsp3
(B) sp3 d
(C) d2 sp3
(D) sp3 d2
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The rate constant for a first order reaction is 100 s–1. The time required for completion of 50% of reaction is _______.
(A) 0.0693 milliseconds
(B) 0.693 milliseconds
(C) 6.93 milliseconds
(D) 69.3 milliseconds
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Derive an expression for maximum work in isothermal reversible expansion of two moles of an ideal gas.
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