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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density of 20% (mass/mass) aqueous KI is 1.202 g mL−1.

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Define mole fraction.

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Define molarity (M).

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Define mass percentage.

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Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is 1.504 g mL−1?

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A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL−1, then what shall be the molarity of the solution?

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How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?

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A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate the mass percentage of the resulting solution.

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An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL−1, then what shall be the molarity of the solution?

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A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):

  1. express this in percent by mass.
  2. determine the molality of chloroform in the water sample.
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If the density of some lake water is 1.25 g mL−1 and contains 92 g of Na+ ions per kg of water, calculate the molality of Na+ ions in the lake.

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If the solubility product of CuS is 6 × 10−16, calculate the maximum molarity of CuS in aqueous solution.

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Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6.5 g of C9H8O4 is dissolved in 450 g of CH3CN.

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Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 × 10−3 m aqueous solution required for the above dose.

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For a reaction, \[\ce{A + B -> Product}\]; the rate law is given by, r = k [A]1/2 [B]2. What is the order of the reaction?

[3] Chemical Kinetics
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The conversion of molecules X to Y follows second order kinetics. If concentration of X is increased to three times how will it affect the rate of formation of Y?

[3] Chemical Kinetics
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From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{3NO_{(g)} -> N2O_{(g)}}\] Rate = k[NO]2

[3] Chemical Kinetics
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From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{H2O2_{( aq)} + 3I^-_{( aq)} + 2H^+ -> 2H2O_{(l)} + I^-_3}\] Rate = k[H2O2][I]

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{CH3CHO_{(g)} -> CH4_{(g)} + CO_{(g)}}\] Rate = k[CH3CHO]3/2

[3] Chemical Kinetics
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From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{C2H5Cl_{(g)} -> C2H4_{(g)} + HCl_{(g)}}\] Rate = k[C2H5Cl]

[3] Chemical Kinetics
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