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Basic principle of hydrogen economy is transportation and storage of energy in the form of liquid or gaseous hydrogen. Which property of hydrogen may be useful for this purpose? Support your answer with the chemical equation if required.
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Benzoic acid is a organic compound. Its crude sample can be purified by crystallisation from hot water. What characteristic differences in the properties of benzoic acid and the impurity make this process of purification suitable?
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Which are the correct IUPAC names of the following compound?
\[\begin{array}{cc}
\ce{H3C - CH2 - CH2 - CH2 - CH - CH2 - CH2 - CH2 - CH2 - CH3}\\
|\phantom{.........}\\
\ce{CH2}\phantom{......}\\
|\phantom{.........}\\
\ce{HC3 - C - CH3}\phantom{.........}\\
|\phantom{.........}\\
\ce{CH3}\phantom{......}
\end{array}\]
(i) 5 – (2′, 2′–Dimethylpropyl)-decane
(ii) 4 – Butyl – 2, 2– dimethylnonane
(iii) 2, 2– Dimethyl – 4– pentyloctane
(iv) 5 – neo-Pentyldecane
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Calculate the amount of carbon dioxide that could be produced when 1 mole of carbon is burnt in air.
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Calculate the amount of carbon dioxide that could be produced when 1 mole of carbon is burnt in 16 g of dioxygen.
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Calculate the amount of carbon dioxide that could be produced when 2 moles of carbon are burnt in 16 g of dioxygen.
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What is the concentration of sugar (C12H22O11) in mol L–1 if its 20 g are dissolved in enough water to make a final volume up to 2 L?
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If the density of methanol is 0.793 kg L–1, what is its volume needed for making 2.5 L of its 0.25 M solution?
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A sample of drinking water was found to be severely contaminated with chloroform, CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
- Express this in percent by mass.
- Determine the molality of chloroform in the water sample.
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Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation:
\[\ce{N2 (g) + 3H2 (g) → 2NH3 (g)}\]
(i) Calculate the mass of ammonia produced if 2.00 × 103 g dinitrogen reacts with 1.00 × 103 g of dihydrogen.
(ii) Will any of the two reactants remain unreacted?
(iii) If yes, which one and what would be its mass?
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Calculate the molarity of a solution of ethanol in water in which the mole fraction of ethanol is 0.040 (assume the density of water to be one).
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An electron is in one of the 3d orbitals. Give the possible values of n, l and ml for this electron.
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The unpaired electrons in Al and Si are present in 3p orbital. Which electrons will experience more effective nuclear charge from the nucleus?
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What is meant by hybridisation of atomic orbitals?
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Describe the shapes of sp, sp2,sp3 hybrid orbitals.
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Describe the change in hybridisation (if any) of the Al atom in the following reaction.
\[\ce{AlCl_3 + Cl- -> AlCl_4-}\]
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Is there any change in the hybridisation of B and N atoms as a result of the following reaction?
\[\ce{BF3 + NH3 → F3B.NH3}\]
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Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why?
- 1s and 1s
- 1s and 2px
- 2py and 2py
- 1s and 2s.
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3–CH3
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For the reaction at 298 K,
\[\ce{2A + B → C}\]
ΔH = 400 kJ mol-1 and ΔS = 0.2 kJ K-1 mol-1
At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?
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