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Which of the following pair of elements would have a more negative electron gain enthalpy?
F or Cl
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Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.
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Describe the theory associated with the radius of an atom as it gains an electron.
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Describe the theory associated with the radius of an atom as it loses an electron.
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Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
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Although geometries of NH3 and H2O molecules are distorted tetrahedral, bond angle in water is less than that of ammonia. Discuss.
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Calculate the total number of electrons present in 1.4 g of dinitrogen gas.
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Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
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2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
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Write IUPAC name of the product obtained by the ozonolysis of the following compound.
Pent-2-ene
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An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. Write structure and IUPAC name of ‘A’.
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An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.
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Propanal and pentan-3-one are the ozonolysis products of an alkene? What is the structural formula of the alkene?
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Write a chemical equation for combustion reaction of the following hydrocarbon:
Butane
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Write a chemical equation for combustion reaction of the following hydrocarbon:
Pentene
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Write a chemical equation for combustion reaction of the following hydrocarbon:
Hexyne
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Write a chemical equation for combustion reaction of the following hydrocarbon:
Toluene
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Explain the following reaction.
Silicon dioxide is treated with hydrogen fluoride.
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If the starting material for the manufacture of silicones is RSiCl3, write the structure of the product formed.
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Bromine monochloride, BrCl decomposes into bromine and chlorine and reaches the equilibrium:
\[\ce{2BrCl (g) ⇌ Br2 (g) + Cl2 (g)}\]
for which Kc= 32 at 500 K. If initially pure BrCl is present at a concentration of 3.3 × 10–3 molL–1, what is its molar concentration in the mixture at equilibrium?
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