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Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Choose the most correct option.
Pressure cooker reduces cooking time for food because _______.
Concept: Vapour Pressure Lowering
Answer the following in one or two sentences.
What is osmotic pressure?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Answer the following in one or two sentences.
What is osmotic pressure?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Answer the following.
What are isotonic and hypertonic solutions?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Answer the following.
What are isotonic and hypertonic solutions?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Derive the relationship between the degree of dissociation of an electrolyte and van’t Hoff factor.
Concept: Colligative Properties of Electrolytes
The vapour pressure of water at 20°C is 17 mm Hg. What is the vapour pressure of solution containing 2.8 g urea in 50 g of water?
Concept: Vapour Pressure of Solutions of Liquids in Liquids
A solution of citric acid C6H8O7 in 50 g of acetic acid has a boiling point elevation of 1.76 K. If Kb for acetic acid is 3.07 K kg mol-1, what is the molality of solution?
Concept: Relative Molecular Mass >> Boiling Point Elevation
A mixture of benzene and toluene contains 30% by mass of toluene. At 30°C, vapour pressure of pure toluene is 36.7 mm Hg and that of pure benzene is 118.2 mm Hg. Assuming that the two liquids form ideal solutions, calculate the total pressure and partial pressure of each constituent above the solution at 30°C.
Concept: Vapour Pressure of Solutions of Liquids in Liquids
The Henry’s law constant of a gas is 6.7 × 10–4 mol/(L bar). Its solubility when the partial pressure of the gas at 298 K is 0.65 bar is ______.
Concept: Solubility
State Raoult’s law.
Concept: Vapour Pressure of Solutions of Liquids in Liquids
The vapour pressures of pure liquids A and B are 0.600 bar and 0.933 bar respectively, at a certain temperature.
What is the mole fraction of liquid B in the solution when the total vapour pressure of their mixture is 0.8 bar?
Concept: Vapour Pressure of Solutions of Liquids in Liquids
For a very dilute solution, the osmotic pressure is given by π = n2RT/V where V is the volume in L containing n2 moles of nonvolatile solute. Establish the equation for molar mass of solute.
Concept: Vapour Pressure Lowering
Give two points to explain why vapour pressure of solvent is lowered by dissolving nonvolatile solute into it.
Concept: Vapour Pressure Lowering
Derive the expression for molar mass of solute in terms of boiling point elevation of solvent.
Concept: Relative Molecular Mass >> Boiling Point Elevation
With the help of vapour pressure-temperature curves for solution and solvent, explain why boiling point of solvent is elevated when a nonvolatile solute is dissolved into it.
Concept: Vapour Pressure of Solutions of Liquids in Liquids
A solution containing 3 g of solute A (M = 60 g/mol) in 1 L solution is isotonic with a solution containing 8.55 g of solute B in 500 mL solution. What is the molar mass of B?
Concept: Relative Molecular Mass >> Boiling Point Elevation
